in gas T=450.1 - 490.6°C; P=65 - 198 Torr; pyrolysis in static system; Ea, log A, ΔH(act.), ΔS(act.); kinetic and mechanism of gas phase elimination of primary, secondary and tertiary 2-hydroxyalkylbenzenes; stoichiometry; effect of inhibitor toluene; Rate constantThermodynamic dataProduct distribution;
参考文献
Chuchani, Gabriel; Rotinov, Alexandra; Dominguez, Rosa M.
International Journal of Chemical Kinetics, 1999 , vol. 31, # 6 p. 401 - 407
1: 40 percent / diphenyl-2-pyridylphosphine; di-tert-butyl azodicarboxylate / CH2Cl2 / 2 h / 20 °C 2: 94 percent / PhSH; potassium carbonate / acetonitrile / 50 °C View Scheme
参考文献
Guisado, Cristina; Waterhouse, Jodie E.; Price, Wayne S.; Jorgensen, Michael R.; Miller, Andrew D.
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 6 p. 1049 - 1057
