2-环己烯-1-基(三甲基)硅烷合成路线 （共 11 条）
反应条件
iodine; magnesium in diethyl ether
12 h; ice-bath temperature;
参考文献
Hitchcock, Peter B.; Lappert, Michael F.; Leung, Wing-Por; Liu, Dian-Sheng; Mak, Thomas C. W.; Wang, Zhong-Xia
Journal of the Chemical Society - Dalton Transactions, 1999 , # 8 p. 1257 - 1262
反应条件
1: in tetrahydrofuran
18 h; RefluxInert atmosphere;
2: With water in tetrahydrofuran
T=0°C;
参考文献
Yoshimura, Yuichi; Ohta, Masatoshi; Imahori, Tatsushi; Imamichi, Tomozumi; Takahata, Hiroki
Organic Letters, 2008 , vol. 10, # 16 p. 3449 - 3452
反应条件
magnesium in tetrahydrofuran
7 h; Heating;
参考文献
Laycock, Bronwyn; Maynard, Ian; Wickham, Geoffrey; Kitching, William
Australian Journal of Chemistry, 1988 , vol. 41, # 5 p. 693 - 700
参考文献
Benkeser,R.A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, p. 1370 - 1376
参考文献
Kiso,Y. et al.
Journal of Organometallic Chemistry, 1973 , vol. 50, p. 297 - 310
参考文献
Hayashi, Tamio; Kabeta, Keiji; Yamamoto, Tsunehiro; Tamao, Kohei; Kumada, Makoto
Tetrahedron Letters, 1983 , vol. 24, # 50 p. 5661 - 5664
反应条件
in water
T=25°C; different solvent/reagent ratio; Product distributionRate constant;
参考文献
Shiner, V. J.; Ensinger, Mark W.
Journal of the American Chemical Society, 1986 , vol. 108, # 4 p. 842 - 844
反应条件
in water
T=25°C; different solvent/reagent ratio; other solvent; Product distributionRate constant;
参考文献
Shiner, V. J.; Ensinger, Mark W.
Journal of the American Chemical Society, 1986 , vol. 108, # 4 p. 842 - 844
反应条件
1: (i) BH3, THF, (ii) /BRN= 2935408/
2: aq. CrO3
View Scheme
参考文献
de Jesus,M. et al.
Journal of Organometallic Chemistry, 1977 , vol. 132, p. 301 - 320
反应条件
trimethylsilyl trifluoromethanesulfonate in dichloromethane
1.) -78 deg C, 15 min, 2.) r.t., 5 d;
参考文献
Roos; Lopez; Brook; Hiemstra; Speckamp
Journal of Organic Chemistry, 1993 , vol. 58, # 12 p. 3259 - 3268
