1-甲氧基-1-丁烯-3-炔合成路线 （共 17 条）
反应条件
hydrogenchloride T=15°C; ΔH(activ.), ΔS(activ.), var. temperatures; Rate constantKineticsThermodynamic data;
参考文献
Vavilova, A. N.; Trofimov, B. A.; Volkov, A. N.; Keiko, V. V.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, p. 809 - 812
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 5 p. 926 - 928
反应条件
in N,N-dimethyl-formamide 3.5 h; Heating;
参考文献
Mavrov, M. V.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, # 4 p. 626 - 632
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 4 p. 710 - 717
反应条件
air in chloroform-d1 1440 h; Ambient temperaturedaylight; Product distribution;
参考文献
Helvetica Chimica Acta, , vol. 70, p. 1400 - 1411
反应条件
n-butyllithium in tetrahydrofuran; hexane 1.) -25 deg C to -20 deg C, 1 h; 2.) 25 deg C, 1 h;
参考文献
Zweifel, George; Rajagopalan, Shyamala
Journal of the American Chemical Society, 1985 , vol. 107, # 3 p. 700 - 701
反应条件
air in chloroform-d1 1440 h; Ambient temperaturedaylight; Product distribution;
参考文献
Guella, Graziano; Mancini, Ines; Pietra, Francesco
Helvetica Chimica Acta, 1987 , vol. 70, p. 1400 - 1411
反应条件
Yield given. Multistep reaction;
参考文献
Maeta, Hideki; Suzuki, Keisuke
Tetrahedron Letters, 1993 , vol. 34, # 2 p. 341 - 344
反应条件
1: 1) 2.5 M n-butyllithium / 1) THF, -78 deg C, 50 min, 2) -78 deg C, 30 min
2: 92 percent / K2CO3 / 2 h
3: 85 percent / p-toluenesulfonic acid / tetrahydrofuran; H2O / 15 h / Heating
4: trifluoroacetic acid / benzene / 72 h
View Scheme
参考文献
Crimmins, Michael T.; O'Mahony, Rosemary
Journal of Organic Chemistry, 1990 , vol. 55, # 23 p. 5894 - 5900
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 1 h, 2.) -78 deg C, 1 h
2: K2CO3 / 16 h
3: 35percent aq. HClO4 / CH2Cl2 / 0.17 h
View Scheme
参考文献
Crimmins, Michael T.; Bankaitis, Danute M.
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4551 - 4554
反应条件
n-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
参考文献
Crimmins, Michael T.; Bankaitis, Danute M.
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4551 - 4554
反应条件
n-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
参考文献
Crimmins, Michael T.; Bankaitis, Danute M.
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4551 - 4554
