in tetrahydrofuran byproducts: chloroethylene; BH3 in THF reacted with org. compd. (molar ratio 1:2) at 20°C for 2 h under Ar; product not isolated, detected by NMR and determination of hydrolysis products;
参考文献
Arase, Akira; Hoshi, Masayuki; Masuda, Yuzuru
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 1 p. 299 - 300
in tetrahydrofuran (N2); addn. of a soln. of boron compd. in THF to a soln. of tin compd. in THF, stirring at room temp. for 1 h, refluxing for 3 h, addn. of water;
参考文献
Mandolesi, Sandra D.; Vaillard, Santiago E.; Podesta, Julio C.; Rossi, Roberto A.
Organometallics, 2002 , vol. 21, # 22 p. 4886 - 4888
in tetrahydrofuran (N2); addn. of a soln. of boron compd. in THF to a soln. of tin compd. in THF, stirring at room temp. for 1 h, refluxing for 3 h, addn. of water;
NH3 byproducts: H2; heating; reacting time from 15 min to 2-3 h;
参考文献
Wiberg, E.; Bolz, A.
Ber., 1940 , vol. 73, p. 209 - 232
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Wiberg, E.; Hertwig, K.; Bolz, A.
Z. Anorg. Chem., 1948 , vol. 256, p. 177 - 216
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Gmelin Handbook: B: SVol.1, 4.2.6, page 159 - 167
pyridine; water in tetrahydrofuran; diethyl ether to Sn compd. in THF added BH3 (B/Sn ratio 1/1) under N2 at room temp., stirred for 1 h, refluxed for 1h, cooled to room temp., added H2O, stirred for 30 min at room temp, extd. with Et2O, dried (MgSO4), heated with pentane, evapd., added Et2O and C5H5N;
参考文献
Pickles, G. M.; Spencer, T.; Thorpe, F. G.; Chopa, A. B.; Podesta, J. C.
Journal of Organometallic Chemistry, 1984 , vol. 260, # 1 p. 7 - 16
