2-甲基-2-环己烯-1-酮合成路线 （共 131 条）
反应条件
1: 96 percent / n-BuLi / tetrahydrofuran; hexane / 1.) -10 deg C, 2 h, 2.) -10 deg C, 1 h; refrigerator, 18 h 2: 9 percent / p-TsOH / tetrahydrofuran / 16 h / 25 °C 3: 50 percent / AgNO3, NCS / acetonitrile; H2O / 0.75 h / 0 °C View Scheme
参考文献
Ranu, Brindaban C.; Sarkar, Dipak C.
Synthetic Communications, 1987 , vol. 17, # 2 p. 155 - 160
反应条件
sodium hydroxide; dihydrogen peroxide in methanol Ambient temperature;
参考文献
Caine, Drury; Stanhope, Bruce
Tetrahedron, 1987 , vol. 43, # 23 p. 5545 - 5556
反应条件
aluminium trichloride; hydroquinone in dichloromethane T=20°C; 24 h;
参考文献
Ferraz, Helena M. C.; Vieira, Tiago O.; Silva Jr., Luiz F.
Synthesis, 2006 , # 16 p. 2748 - 2752
参考文献
Wallach
Justus Liebigs Annalen der Chemie, 1908 , vol. 359, p. 292
Justus Liebigs Annalen der Chemie, 1908 , vol. 360, p. 29
反应条件
1: 68 percent / toluene / 4 h / Heating 2: 71 percent / tetrahydrofuran; diethyl ether 3: 67 percent / PCC; SiO2 / CH2Cl2 / 1 h / 20 °C View Scheme
参考文献
Kim, Hee Jin; Koo, Sangho
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 19 p. 3479 - 3481
反应条件
hydrogen; HRuCl(TBPC)2 in benzene T=80°C; P=30400 Torr; 22 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Massonneau, Viviane; Maux, Paul Le; Simonneaux, Gerard
Journal of Organometallic Chemistry, 1987 , vol. 327, p. 269 - 274
参考文献
Jung, Michael E.; Allen, Damian A.
Organic Letters, 2008 , vol. 10, # 10 p. 2039 - 2041
反应条件
lithium aluminium tetrahydride; 4,7,13,18-tetraoxa-1,10-diazabicyclo[8.5.5]eicosane in tetrahydrofuran 0.0833333 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Loupy, Andre; Seyden-Penne, Jacqueline
Tetrahedron, 1980 , vol. 36, p. 1937 - 1942
反应条件
sodium tetrahydroborate; alpha-cyclodextrin in water influence of other cyclodextrin on the reduction; Product distribution;
参考文献
Chenevert, Robert; Chamberland, Daniel
Chemistry Letters, 1985 , p. 1117 - 1118
参考文献
Wallach; Franke
Justus Liebigs Annalen der Chemie, 1903 , vol. 329, p. 375
