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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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2-苯基吡啶
合成路线
(共 355 条)
591-50-4
碘苯
→
反应条件
1008-89-5
2-苯基吡啶
+
3558-69-8
2,6-二苯基吡啶
反应条件
bis-triphenylphosphine-palladium(II) chloride in xylene T=140°C; Phenylation; 24 h;
参考文献
Synlett, , # 2 p. 230 - 232
694-59-7
吡啶-N-氧化物
+
5123-13-7
5,5-二甲基-2-苯基-1,3,2-二氧硼杂
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
copper acetylacetonate; potassium tert-butylate; oxygen in toluene T=110°C; 2 h;
参考文献
Shen, Yan; Chen, Jiuxi; Liu, Miaochang; Ding, Jinchang; Gao, Wenxia; Huang, Xiaobo; Wu, Huayue
Chemical Communications, 2014 , vol. 50, # 33 p. 4292 - 4295
110-86-1
吡啶
+
688-61-9
三烯丙基硼烷
+
591-51-5
苯基锂
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
1: pyridine; phenyllithium in diethyl ether T=0°C; Addition; 1 h; 2: BAll3 in diethyl ether T=-30 - 10°C; coordination; 0.5 h; 3: With methanol in diethyl ether T=-30 - 20°C; allylation;
参考文献
Bubnov; Klimkina; Dekaprilevich; Struchkov
Russian Chemical Bulletin, 1996 , vol. 45, # 11 p. 2595 - 2597
66003-78-9
→
反应条件
1008-89-5
2-苯基吡啶
+
139-66-2
反应条件
pyridin-2-yllithium in tetrahydrofuran; hexane T=0°C; 2 h; other reagents: phenyllithium, 2-thienyllithium, 2-quinolyllithium, 2-furyllithium, 2-pyrimidyllithium, n-butyllithium;
参考文献
Russian Journal of Organic Chemistry, , vol. 32, # 2 p. 265 - 269
110-86-1
吡啶
+
591-50-4
碘苯
→
反应条件
1008-88-4
+
1008-89-5
2-苯基吡啶
+
939-23-1
反应条件
potassium tert-butylate T=110°C; 5 h;
参考文献
New Journal of Chemistry, , vol. 38, # 2 p. 827 - 836
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
N-hexadecyl-N,N,N-trimethylammonium bromide; palladium; triethylamine in water T=110°C; Suzuki-Miyaura Coupling; 0.5 h; Microwave irradiation; Reagent/catalyst;
参考文献
Civicos, Jose F.; Alonso, Diego A.; Najera, Carmen
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 14-15 p. 2771 - 2776
110-86-1
吡啶
+
58109-40-3
→
反应条件
1008-88-4
+
1008-89-5
2-苯基吡啶
+
939-23-1
反应条件
[(2-phenylpyridine(-H))2IrIII(2,2′-bipyridine)]PF6 T=20°C; 16 h; Inert atmosphereIrradiation; Reagent/catalyst; Overall yield = 57 percent;
参考文献
Chemistry Letters, , vol. 42, # 10 p. 1203 - 1205
109-04-6
+
780-69-8
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
1: monophenyl triethoxy silane With cesium fluoride in 1-methyl-pyrrolidin-2-one T=20°C; 1 h; 2: 2-bromo-pyridine With (1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)2Pd2Cl6 in 1-methyl-pyrrolidin-2-one T=20 - 100°C; Hiyama Coupling; 0.133333 h; Microwave irradiation; TemperatureTime;
参考文献
Hajipour, Abdol R.; Rafiee, Fatemeh; Najafi, Narges
Applied Organometallic Chemistry, 2014 , vol. 28, # 4 p. 217 - 220
65007-00-3
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0); 2-dicyclohexylphosphino-1,1'-biphenyl in 1,4-dioxane 6 h; Heating;
参考文献
Seganish, W. Michael; DeShong, Philip
Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1137 - 1143
853955-69-8
+
109-04-6
→
反应条件
1008-89-5
2-苯基吡啶
+
321903-29-1
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide T=75°C; 22 h; Inert atmosphere;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 83, # 5 p. 554 - 569
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