copper(l) chloride in neat (no solvent) mixt. of Ge and CuCl was pretreated at 450°C for 1 h under He; mixt. of HCl and C2H4 was fed at 450°C; not isolated; gas chromd.;
in solid byproducts: propyl trichlorogermane; passing through quartz tubular reactor, 650°C, 30 s (yield of EtGeCl3 0.3percent at temperatures 550°C); product condensation, distillation (under atmospheric pressure; then in vaccum);
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Yakovleva, G. N.; Bykovchenko, V. G.; Khromykh, N. N.; et al.
Russian Journal of General Chemistry, 1999 , vol. 69, p. 90 - 92
Zhurnal Obshchei Khimii, 1999 , vol. 69, p. 94 - 96
in gas byproducts: butyl(trichlorosilyl)ethane, bis(trichlorosilyl)ethylene, 1-(trichlorogermyl)-2-(trichlorosilyl)ethane; passing through tubular quartz reactor (30 s, 500°C); condensate distillation under atmospheric pressure (GeCl4, SiCl4), vacuum distillation giving the rest of products and EtGeCl3;
参考文献
Russian Journal of General Chemistry, , vol. 68, # 3 p. 403 - 406
