2,2,2-三甲基苯乙酮合成路线 （共 203 条）
参考文献
Nef
Justus Liebigs Annalen der Chemie, 1900 , vol. 310, p. 323
参考文献
Swan
Journal of the Chemical Society, 1948 , p. 1408,1411
反应条件
1: With tris[3,5-bis(2,2'',6,6''-tetramethyl-m-terphenyl-5'-yl)phenyl]phosphine; copper(l) chloride; sodium t-butanolate in toluene T=20°C; 2.5 h; Inert atmosphere; 2: With hydrogenchloride; methanol in toluene Inert atmosphere;
参考文献
Fujihara, Tetsuaki; Semba, Kazuhiko; Terao, Jun; Tsuji, Yasushi
Angewandte Chemie - International Edition, 2010 , vol. 49, # 8 p. 1472 - 1476
反应条件
hydroxylamine hydrochloride; trifluoroacetic acid T=70°C; Beckmann Rearrangement; 16 h; Inert atmosphere;
参考文献
Arico, Fabio; Quartarone, Giuseppe; Rancan, Elia; Ronchin, Lucio; Tundo, Pietro; Vavasori, Andrea
Catalysis Communications, 2014 , vol. 49, p. 47 - 51
反应条件
methyl-magnesium chloride in tetrahydrofuran; perdeuterocyclohexane T=60°C; 2 h; sealed tube;
参考文献
Knorr; Boehrer; Schubert
Chemistry - A European Journal, 2012 , vol. 18, # 24 p. 7506 - 7515
参考文献
Haller; Bauer
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 129
反应条件
hydroxylamine hydrochloride; trifluoroacetic acid T=70°C; Beckmann Rearrangement; 16 h; Inert atmosphere;
参考文献
Arico, Fabio; Quartarone, Giuseppe; Rancan, Elia; Ronchin, Lucio; Tundo, Pietro; Vavasori, Andrea
Catalysis Communications, 2014 , vol. 49, p. 47 - 51
反应条件
in tert-butyl alcohol T=21°C; Irradiation; Product distributionMechanism;
参考文献
Journal of Physical Chemistry, , vol. 84, # 25 p. 3467 - 3474
反应条件
sodium tetrahydroborate in methanol; ethanol 2 h;
参考文献
Journal of Organic Chemistry, , vol. 51, # 8 p. 1341 - 1346
反应条件
hydrogen in toluene T=80°C; P=15001.5 Torr; 24 h; Autoclave; chemoselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8071 - 8077
