diphenyldisulfane in benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial and PhSSPh (1.2 equiv) in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 4h);; filtration; solvent removed (vacuum); PhCH2CH2Ph and PhCH2SPh analysed by (1)H NMR, GLC and GCMS;;
参考文献
Journal of the American Chemical Society, , vol. 110, # 11 p. 3530 - 3538
1: phenyl N,N-diethyldithiocarbamate With potassium hydroxide in water T=110°C; 4 h; 2: benzyl bromide in water T=20°C; 1 h; Reagent/catalystSolventTemperature;