1,1,1,2-四氟乙烷合成路线 （共 120 条）
反应条件
oxygen; sulphur(VI) hexafluoride in gas T=21.9°C; pulse radiolysis; other gas mixtures; generation of radicals; self reactions of CF3CFCHO2; self reactions of CF3O2 radicals; cross reactions of HO2 radicals with CF3CFHO2 radicals and with CF3O2 radicals; Rate constant;
参考文献
Sehested; Mogelberg; Fagerstrom; Mahmoud; Wallington
International Journal of Chemical Kinetics, 1997 , vol. 29, # 9 p. 673 - 682
反应条件
oxygen; chlorine T=19.9°C; P=760 Torr; Irradiationfurther temp.; Product distributionMechanism;
参考文献
Rattigan, Oliver V.; Rowley, David M.; Wild, Oliver; Jones, Roderic L.; Cox, R. Anthony
Journal of the Chemical Society, Faraday Transactions, 1994 , vol. 90, # 13 p. 1819 - 1830
反应条件
air; water; chlorine T=22.9°C; P=700 Torr; Irradiationother partial pressures of the components; reaction without water; Product distribution;
参考文献
Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John
Journal of Physical Chemistry, 1993 , vol. 97, # 29 p. 7606 - 7611
反应条件
oxygen; chlorine T=21.9°C; P=750.06 Torr; 0.5 h; Irradiationvar. of temp., partial pressure, also addition of NO, Ea; Rate constantMechanismThermodynamic data;
参考文献
Bednarek; Ereil; Hoffmann; Kohlmann; Moers; Zellner
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996 , vol. 100, # 5 p. 528 - 539
反应条件
fluorine T=200 - 250°C; Product distribution; Further Variations:Reagents;
参考文献
Russian Journal of Applied Chemistry, , vol. 75, # 8 p. 1269 - 1274
反应条件
1: 1,1,1-trifluoro-2-fluoroethane With zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran T=15 - 20°C; 2: 4-fluoro-1-iodobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=65°C; 4 h;
参考文献
Raghavanpillai, Anilkumar; Burton, Donald J.
Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7083 - 7091
反应条件
fluorine T=-20°C; Fluorination; 0.4 h; Title compound not separated from byproducts;
参考文献
Moldavskii, Dmitrii D.; Bispen, Tatjana A.; Kaurova, Galina I.; Furin, Georgii G.
Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 157 - 167
反应条件
cobalt(III) fluoride T=220°C; 0.000277778 h; var. fluorinating agents and temp.; Product distribution;
参考文献
Russian Journal of Applied Chemistry, , vol. 68, # 1part2 p. 131 - 132
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), , vol. 68, # 1 p. 149 - 150
反应条件
fluorine T=45 - 60°C; Fluorination; 2.5 h; Product distribution; Further Variations:Temperatures;
参考文献
Moldavskii, Dmitrii D.; Bispen, Tatjana A.; Kaurova, Galina I.; Furin, Georgii G.
Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 157 - 167
反应条件
fluorine T=200 - 250°C; Product distribution; Further Variations:Reagents;
参考文献
Russian Journal of Applied Chemistry, , vol. 75, # 8 p. 1269 - 1274
