1,1,1,2-四氟乙烷合成路线 (共 120 条)
反应条件
fluorine T=45 - 60°C; Fluorination; 2.5 h; Product distribution; Further Variations:Temperatures;
参考文献
Moldavskii, Dmitrii D.; Bispen, Tatjana A.; Kaurova, Galina I.; Furin, Georgii G.
Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 157 - 167
反应条件
basic zeolite T=275°C; 17 h; dehydrofluorination, various time; Product distribution;
参考文献
SOLVAY FLUOR GmbH; Humboldt-Universitaet zu Berlin
Patent: WO2009/10472 A1, 2009 ;
Location in patent: Page/Page column 21 ;
反应条件
T=1006.9°C; gas-phase reaction, thermal and thermooxidative stability, various degree of adiabatic compression or various maximum temperature in adiabatic compression pulse, oxygen presence or absence; Product distributionMechanismKinetics;
参考文献
Buravtsev, N. N.; Grigor'ev, A. S.; Kolbanovskii, Yu. A.; Ovsyannikov, A. A.
Russian Journal of Organic Chemistry, 1994 , vol. 30, # 12 p. 1880 - 1890
Zhurnal Organicheskoi Khimii, 1994 , vol. 30, # 12 p. 1794 - 1801
反应条件
cobalt(III) fluoride T=220°C; 0.000277778 h; var. fluorinating agents and temp.; Product distribution;
参考文献
Russian Journal of Applied Chemistry, , vol. 68, # 1part2 p. 131 - 132
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), , vol. 68, # 1 p. 149 - 150
反应条件
fluorine T=105°C; Substitution; Activation energy; Further Variations:Temperaturesconcentration dependence;
参考文献
Pashkevich; Muhortov; Podpalkina; Barabanov
Journal of Fluorine Chemistry, 1999 , vol. 96, # 1 p. 3 - 5
反应条件
fluorine T=45 - 60°C; Fluorination; 2.5 h; Product distribution; Further Variations:Temperatures;
参考文献
Moldavskii, Dmitrii D.; Bispen, Tatjana A.; Kaurova, Galina I.; Furin, Georgii G.
Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 157 - 167
反应条件
fluorine T=200 - 250°C; Product distribution; Further Variations:Reagents;
参考文献
Russian Journal of Applied Chemistry, , vol. 75, # 8 p. 1269 - 1274
反应条件
hydrogen; oxygen; fluorine in gaseous matrix T=-63.1 - 89.9°C; P=200 Torr; Irradiationacivation energy data for intermediate rections; KineticsMechanismThermodynamic data;
参考文献
Maricq, M. Matti; Szente, Joseph J.; Hurley, Michael D.; Wallington, Timothy J.
Journal of Physical Chemistry, 1994 , vol. 98, # 36 p. 8962 - 8970
反应条件
hydrogen; oxygen; chlorine in gaseous matrix T=22.9°C; P=700 Torr; Irradiation; Product distribution;
参考文献
Maricq, M. Matti; Szente, Joseph J.; Hurley, Michael D.; Wallington, Timothy J.
Journal of Physical Chemistry, 1994 , vol. 98, # 36 p. 8962 - 8970
反应条件
oxygen; chlorine T=21.9°C; P=800 Torr; Irradiationalso in the presence of NO; Rate constant;
参考文献
Hasson; Moore; Smith
International Journal of Chemical Kinetics, 1998 , vol. 30, # 8 p. 541 - 554