sulfuric acid in acetonitrile T=10°C; 0.5 h; Mechanism;

dichloro bis(acetonitrile) palladium(II); caesium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in water; tert-butyl alcohol T=100°C; Suzuki-Miyaura cross-coupling; Inert atmosphere;

Wilkinson's catalyst; potassium carbonate T=120°C; 12 h; Sealed tube;

[RuCl(CO)(PPh3)(PNS-Me)]; potassium hydroxide in toluene T=100°C; 12 h;

triethylsilane; dirhenium heptaoxide in dichloromethane T=20°C; 12 h; chemoselective reaction;

hydrogenchloride; samarium in tetrahydrofuran T=20°C; Title compound not separated from byproducts;

1.1: potassium hexamethylsilazane / tetrahydrofuran / 2.25 h / -78 - 20 °C / Inert atmosphere 1.2: 1 h / 0 °C / Inert atmosphere 1.3: 2 h / 0 - 20 °C / Inert atmosphere 2.1: KHF2 / methanol; water / 1 h / 0 - 20 °C 3.1: dichloro bis(acetonitrile) palladium(II); caesium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine / water; tert-butyl alcohol / 100 °C / Inert atmosphere View Scheme

暂无反应条件数据

in acetonitrile T=65°C; Kinetics;

in acetonitrile T=65°C; Kinetics;