三甲基(4-苯基丁基)硅烷合成路线 （共 13 条）
反应条件
1: 61 percent / PBr3
2: 50 percent / Li
View Scheme
参考文献
Maercker, Adalbert; Passlack, Michael
Chemische Berichte, 1982 , vol. 115, # 2 p. 540 - 577
参考文献
Maercker, Adalbert; Passlack, Michael
Chemische Berichte, 1982 , vol. 115, # 2 p. 540 - 577
反应条件
1: LiAlH4 / diethyl ether
2: (i) TsCl, Py, Et2O, (ii) LiBr, acetone
3: Mg / tetrahydrofuran
View Scheme
参考文献
Weber,W.P. et al.
Journal of Organic Chemistry, 1971 , vol. 36, p. 1620 - 1626
反应条件
1: 56 percent / Mg / diethyl ether / Heating
2: 43 g / NBS, dibenzoylperoxide / CCl4 / 3 h / Heating
3: 3 percent / Mg / diethyl ether; tetrahydrofuran / 2 h / Heating
4: tetrahydrofuran-d8 / 2 °C
View Scheme
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. C40 - C46
反应条件
1: 43 g / NBS, dibenzoylperoxide / CCl4 / 3 h / Heating
2: 3 percent / Mg / diethyl ether; tetrahydrofuran / 2 h / Heating
3: tetrahydrofuran-d8 / 2 °C
View Scheme
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. C40 - C46
反应条件
1: 3 percent / Mg / diethyl ether; tetrahydrofuran / 2 h / Heating
2: tetrahydrofuran-d8 / 2 °C
View Scheme
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. C40 - C46
反应条件
in THF-d8 (tetrahydrofuran-d8)
T=2°C;
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. C40 - C46
反应条件
W(N(2,6-disopropylphenyl))(C3H6)(pyrrolyl)(O-2,6-(2,4,6-i-Pr3C6H2)2C6H3); (tBuPOCOP)Ir(C2H4)
T=150°C; Cross Metathesis; 48 h; Schlenk technique;
参考文献
Dobereiner, Graham E.; Yuan, Jian; Schrock, Richard R.; Goldman, Alan S.; Hackenberg, Jason D.
Journal of the American Chemical Society, 2013 , vol. 135, # 34 p. 12572 - 12575
反应条件
α-Methylbenzyllithium
1.) THF-d8, 2.) THf-d8; Yield given. Multistep reaction;
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. C40 - C46
反应条件
1: 79 percent / LiAlH4
2: 61 percent / PBr3
3: 50 percent / Li
View Scheme
参考文献
Maercker, Adalbert; Passlack, Michael
Chemische Berichte, 1982 , vol. 115, # 2 p. 540 - 577
