1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯合成路线 （共 35 条）
反应条件
1: methyl acetate With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane T=0°C; 0.333333 h; 2: tert-butyldimethylsilyl chloride With N,N'-dimethyl-N,N'-propyleneurea in tetrahydrofuran; hexane T=-78 - 20°C; Further stages.;
参考文献
Wenzel, Anna G.; Jacobsen, Eric N.
Journal of the American Chemical Society, 2002 , vol. 124, # 44 p. 12964 - 12965
反应条件
zinc(II) iodide in acetonitrile T=70°C; 8 h; Yield given. Yields of byproduct given;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 40, # 1 p. 12 - 20
反应条件
1,3-bis(1-adamantyl)imidazolin-2-ylidene in tetrahydrofuran T=23°C; 20 h; Inert atmosphere;
参考文献
Song, Jinhua J.; Tan, Zhulin; Reeves, Jonathan T.; Fandrick, Daniel R.; Yee, Nathan K.; Senanayake, Chris H.
Organic Letters, 2008 , vol. 10, # 5 p. 877 - 880
反应条件
1,3-bis(1-adamantyl)imidazolin-2-ylidene in tetrahydrofuran T=23°C; 20 h; Inert atmosphere;
参考文献
Song, Jinhua J.; Tan, Zhulin; Reeves, Jonathan T.; Fandrick, Daniel R.; Yee, Nathan K.; Senanayake, Chris H.
Organic Letters, 2008 , vol. 10, # 5 p. 877 - 880
反应条件
tetrachlorosilane; (R,R)-N,N'-bis(phosphoramide)-N,N'-Me2-1,5-pentanediamine in dichloromethane T=-78°C; 0.25 h; Title compound not separated from byproducts;
参考文献
Denmark, Scott E.; Eklov, Brian M.; Yao, Peter J.; Eastgate, Martin D.
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11770 - 11787
反应条件
1: 75 percent / zinc iodide / acetonitrile / r.t. 1 h., 70 deg C. 14 h. 2: 61 percent / Raney nickel / ethanol / 0.5 h / Ambient temperature View Scheme
参考文献
Kita, Yasuyuki; Tamura, Osamu; Yasuda, Hitoshi; Itoh, Fumio; Tamura, Yasumitsu
Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 10 p. 4235 - 4241
反应条件
Yield given. Multistep reaction;
参考文献
Colvin; McGarry; Nugent
Tetrahedron, 1988 , vol. 44, # 13 p. 4157 - 4172
反应条件
Yield given. Multistep reaction;
参考文献
Colvin, Ernest W.; McGarry, Daniel G.
Journal of the Chemical Society, Chemical Communications, 1985 , # 9 p. 539 - 540
反应条件
tetrachlorosilane; (R,R)-N,N'-bis(phosphoramide)-N,N'-Me2-1,5-pentanediamine in dichloromethane T=-78°C; 0.25 h; Title compound not separated from byproducts;
参考文献
Denmark, Scott E.; Eklov, Brian M.; Yao, Peter J.; Eastgate, Martin D.
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11770 - 11787
反应条件
lithium perchlorate in diethyl ether P=760 Torr; 1.6 h; Ambient temperature;
参考文献
Grieco; Cooke; Henry; Vander-Roest
Tetrahedron Letters, 1991 , vol. 32, # 36 p. 4665 - 4668
