1: trimethylsilyltriphenyltin With phenylytterbium iodide in tetrahydrofuran T=25°C; Metallation; 3 h; 2: iodobenzene With NiCl2((PPh3)P)2 in tetrahydrofuran Phenylation;
参考文献
Rybakova; Syutkina; Petrov
Russian Journal of General Chemistry, 2000 , vol. 70, # 2 p. 244 - 246
hydrogenchloride in tetrahydrofuran mixing of MnBu2 with Li-salt in THF (molar ratio 1:1.5, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Negishi, Ei-ichi; Akiyoshi, Kazunari; O'Connor, Brian; Takagi, Kentaro; Wu, Guangzhong
Journal of the American Chemical Society, 1989 , vol. 111, # 8 p. 3089 - 3091
hydrogenchloride in tetrahydrofuran mixing of Zr-complex with Li-salt in THF (molar ratio 1:1.5, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N aq. HCl;
参考文献
Journal of the American Chemical Society, , vol. 111, # 8 p. 3089 - 3091
