反应条件
silver carbonate in methanol byproducts: AgCl; addn. of Ag2CO3 to a suspension of trans-(CoCl2en2)NO3 in methanol-HF-mixture; heating of the -70°C cold mixture in 30 min to room temperature; filtration; pptn. on cooling;; dissolving in a small amount of H2O; addn. of excess NH4NO3; fractionated crystallization on addn. of methanol, acetone and ether;;
参考文献
Matoush, R.; Basolo, F.
Journal of the American Chemical Society, 1956 , vol. 78, p. 3972 - 3976
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Gmelin Handbook: Co: SVol.B2, 94, page 510 - 513
