xylene; iron xylene/ferrocene mixt. continuously injected into preheater (.approx. 200°C) on TiN; stream of Ar/H2 gas sweeps the vapors of xylene/ferrocene into the furnace (at .appox.700°C);
silica gel; iron in gaseous matrix byproducts: HCl, CN, N2; pyrolysis of org. compd. over laser-etched Fe films deposited on an inverted silica substrate; Ar flow; 950°C; determined by scanning electron microscopy, high resolution transmissionelectron microscopy, energy dispersive X-ray analyses, electron diffrac tion studies;
参考文献
Chemical Physics Letters, , vol. 285, # 5-6 p. 299 - 305
in neat (no solvent) byproducts: H2O; glucose de-watered in air at 180°C for 24 h, crushed, heated at 1°C/min to pyrolysis temp. (1000 or 1150°C) under Ar (ca 100 cm**3/min) in Lindberg tube furnace;
参考文献
Journal of the Electrochemical Society, , vol. 147, # 4 p. 1271 - 1273
catalyst:7 wtpercentNi/MgO in neat (no solvent) Kinetics; 973 K, 33 kPa CH4 and 33 kPa H2O, resp., or 873 K, 20 kPa CH4, 25 kPa H2O partial pressure, Ar as balance, 7 wtpercentNi/MgO as catalyst;
参考文献
Journal of Catalysis, , vol. 224, # 2 p. 370 - 383
in neat (no solvent) Kinetics; on heating in vac. up to 540°C; 22percent decompn. in 1h, 70percent decompn. in 4h; (vaporization of Al causes decrease of yield);;
参考文献
Journal de Chimie Physique et de Physico-Chimie Biologique, , vol. 13, p. 351 - 351
