ammonia; sodium in methanol
CS2 reduced with Na in DMF at 20°C for 16 h; reacted with ZnCl2 and MeOHsoln. of NH3; reacted with Et4NBr in H2O at 20°C for 16 h;according to J. C. Lodmell et al., Anal. Chim. Acta, 1981, 129, 49;
in methanol
byproducts: NH4Br; under N2, react. of equimolar amts. of educts in methanol; filtered, evapd., extd. with CH2Cl2, evapd. in vac., dried in vac. at 373 K for 1 h;
参考文献
Dillon, Keith B.; Platt, Andrew W. G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 1159 - 1164
in butan-1-ol
washing with butanol, drying in vac.;
参考文献
Cotton, F. A.; Faut, O. D.; Goodgame, D. M.
Journal of the American Chemical Society, 1961 , vol. 83, p. 344 - 351
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Gmelin Handbook: Ni: MVol.C2, 8.18.1, page 1041 - 1052