hydrogen; diethylphosphinoethane; dicobalt octacarbonyl in various solvent(s) T=205°C; P=129200 Torr; 5 h; other temperatures, time; cobalt-catalyzed reaction of paraformaldehyde with synthesis gas; mechanism of homogeneous hydrogenation of carbon monoxyde to alcohols, polyols, and esters; formaldehyde as the key intermediate; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 103, # 1 p. 136 - 141
