(N.N-二乙基)氨基二甲基氯硅烷合成路线 （共 16 条）
参考文献
Hoffmann, Florian; Wagler, Joerg; Roewer, Gerhard
European Journal of Inorganic Chemistry, 2010 , # 7 p. 1133 - 1142
反应条件
dimethyl-dichlorosilane T=20°C; 6 h;
参考文献
Chrusciel
Canadian Journal of Chemistry, 2000 , vol. 78, # 11 p. 1405 - 1411
反应条件
in tetrahydrofuran T=0°C;
参考文献
Organic Letters, , vol. 5, # 22 p. 4231 - 4234
反应条件
in diethyl ether GaCl3 was dissolved in diethyl ether, stirred soln. was cooled in an ice bath, addn. of the silane, the soln. was refluxed for 7 h, pptn., all steps under N2 or Ar; the liquid portion was removed from the solid by vacuum distn., the solid was recrystd. (CH2Cl2), elem. anal.;
参考文献
Inorganic Chemistry, , vol. 30, p. 4136 - 4140
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 24, p. 226 - 230
反应条件
LiF in acetonitrile 40 h; Heating;
参考文献
Hensen, Karl; Pickel, Peter
Liebigs Annalen der Chemie, 1980 , # 2 p. 223 - 228
参考文献
Meyer, Christophe; Cossy, Janine
Tetrahedron Letters, 1997 , vol. 38, # 45 p. 7861 - 7864
反应条件
lithium aluminium tetrahydride in diethyl ether 2.5 h; Heating;
参考文献
Chrusciel
Canadian Journal of Chemistry, 2000 , vol. 78, # 11 p. 1405 - 1411
反应条件
1: 1,1'‐ethyne‐1,2‐diylbis(2‐bromo‐5‐methoxybenzene) With n-butyllithium in diethyl ether; hexane
T=-30 - -25°C; 4 h;
2: Et2NMe2SiCl in diethyl ether; hexane
T=-25°C; 12.5 h;
3: ethanol With ammonium chloride in tetrahydrofuran; hexane
T=20°C; 23 h;
参考文献
Japan Science and Technology Agency
Patent: EP1548019 A1, 2005 ;
Location in patent: Page/Page column 8-9 ;
反应条件
1: 2-bromo-1-[2-(trimethylsilyl)ethynyl]benzene With n-butyllithium in diethyl ether; hexane
T=-78°C; 2.5 h;
2: Et2NMe2SiCl in diethyl ether; hexane
T=-78 - 20°C;
3: ethanol With ammonium chloride in diethyl ether; hexane
T=20°C; 5 h;
参考文献
Mouri, Kazuhiro; Wakamiya, Atsushi; Yamada, Hiroshi; Kajiwara, Takashi; Yamaguchi, Shigehiro
Organic Letters, 2007 , vol. 9, # 1 p. 93 - 96
