2,7-二甲基-3,5-辛二炔-2,7-二醇合成路线 （共 40 条）
参考文献
Sal'kind; Mel'tewa
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 990,991, 996
Chem.Abstr., 1949 , p. 130
反应条件
hydrogenchloride T=60 - 70°C;
参考文献
Skallebol,L.
Tetrahedron, 1965 , vol. 21, p. 1357 - 1367
反应条件
1: K2CO3 / 180 - 190 °C 2: H2 / Pd / ethyl acetate View Scheme
参考文献
Gusev,B.I.; Kucherov,V.F.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1962 , p. 995 - 999
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1962 , # 6 p. 1062 - 1067
反应条件
quinoline; palladium Hydrogenation;
参考文献
Audier
Annales de Chimie (Cachan, France), 1957 , vol. <13> 2, p. 105,110, 125
Full Text Show Details
Audier et al.
Bulletin de la Societe Chimique de France, 1957 , p. 248,251
反应条件
sodium hydroxide; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-benzyl-N,N,N-triethylammonium chloride in 1,4-dioxane; water 1 h; Heating;
参考文献
Sarkar, Abhijit; Okada, Shuji; Nakanishi, Hachiro; Matsuda, Hiro
Helvetica Chimica Acta, 1999 , vol. 82, # 1 p. 138 - 141
反应条件
carbon dioxide; sodium acetate; copper dichloride in methanol
T=40°C; P=105008 Torr; 4 h;
参考文献
Jiang, Huan-Feng; Tang, Jin-Yu; Wang, A.-Zhong; Deng, Guo-Hua; Yang, Shao-Rong
Synthesis, 2006 , # 7 p. 1155 - 1161
反应条件
copper acetylacetonate; iron (III) acetylacetonate; potassium carbonate in N,N-dimethyl-formamide
T=50°C; 12 h;
参考文献
Meng, Xu; Li, Chuanbin; Han, Baochun; Wang, Tiansheng; Chen, Baohua
Tetrahedron, 2010 , vol. 66, # 23 p. 4029 - 4031
反应条件
copper(l) iodide; ethyl α,α-dibromoacetoacetate; triethylamine in dichloromethane
T=20°C; 23 h; Overall yield = 99 percent;
参考文献
Fan, Xiaohui; Li, Na; Shen, Tong; Cui, Xiao-Meng; Lv, Hao; Zhu, Hong-Bo; Guan, Yong-Hong
Tetrahedron, 2014 , vol. 70, # 2 p. 256 - 261
反应条件
copper(l) iodide; NiII chloride hexahydrate; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran
T=20°C; 1 h; Inert atmosphereDarkness;
参考文献
Ahmad, Sohail; Yadav, Kumar Karitkey; Singh, Sarangthem Joychandra; Chauhan
RSC Advances, 2014 , vol. 4, # 7 p. 3171 - 3180
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; N,N-dimethyl-formamide
T=20°C; Alkylation; cross-coupling;
参考文献
Dabdoub, Miguel J.; Dabdoub, Vania B.; Marino, Joseph P.
Tetrahedron Letters, 2000 , vol. 41, # 4 p. 437 - 440
