环戊-1-烯-1-乙酸乙酯合成路线 （共 24 条）
参考文献
Kon; Linstead; Maclennan
Journal of the Chemical Society, 1932 , p. 2453
反应条件
T=100°C; Isomerisierung; Kinetics;
参考文献
Kon; Nargund
Journal of the Chemical Society, 1934 , p. 623,624, 625, 628
反应条件
1: With toluene-4-sulfonic acid in benzene
Dehydration;
2: With lithium diisopropyl amide in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide
Metallation;
3: Hydrolysis; Acid hydrolysis;
参考文献
Urabe; Suzuki; Sato
Journal of the American Chemical Society, 1997 , vol. 119, # 42 p. 10014 - 10027
反应条件
n-butyllithium; diisopropylamine in tetrahydrofuran
T=-78°C; 0.583333 h; Inert atmosphere;
参考文献
Morrill, Louis C.; Smith, Samuel M.; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1640 - 1655
反应条件
lithium dimethyl cuprate in N,N,N',N',N'',N''-hexamethylphosphoric triamide; diethyl ether
T=-30 - 0°C; 1 h;
参考文献
Ibuka, Toshiro; Chu, G.-Namg; Yoneda, Fumio
Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3247 - 3250
反应条件
1.1: 90 percent / LDA
2.1: TsOH / benzene
2.2: LDA / hexamethylphosphoric acid triamide; tetrahydrofuran
2.3: 70 percent / Acid hydrolysis
View Scheme
参考文献
Urabe; Suzuki; Sato
Journal of the American Chemical Society, 1997 , vol. 119, # 42 p. 10014 - 10027
反应条件
lithium dimethyl cuprate in N,N,N',N',N'',N''-hexamethylphosphoric triamide; diethyl ether
T=-30 - 0°C; 1 h;
参考文献
Ibuka, Toshiro; Chu, G.-Namg; Yoneda, Fumio
Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3247 - 3250
参考文献
Kon; Linstead; Maclennan
Journal of the Chemical Society, 1932 , p. 2453
Full Text Show Details
Comp. de Bethune
Patent: US1965792 , 1932 ;
Full Text Show Details
Comp. de Bethune
Patent: FR728998 , 1932 ;
Full Text Show Details
Comp. de Bethune
Patent: DE580450 , 1932 ;
反应条件
potassium hydrogensulfate
T=160 - 180°C;
参考文献
Kon; Nargund
Journal of the Chemical Society, 1932 , p. 2461
反应条件
1: in chloroform
Wittig reaction; 10 h; Reflux;
2: With 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran
10 h; Reflux;
参考文献
Chang, Meng-Yang; Lin, Chung-Han; Chen, Yeh-Long; Hsu, Ru-Ting; Chang, Ching-Yao
Tetrahedron Letters, 2010 , vol. 51, # 23 p. 3154 - 3158
