2,3-二甲基-1-丁烯合成路线 (共 167 条)
反应条件
1: 13 percent Chromat. / γ-Al2O3 / 300 °C / variation of temperature and reagent 2: 27 percent / NaX zeolite / 300 °C View Scheme
参考文献
Tetrahedron, , vol. 43, # 1 p. 131 - 142
反应条件
in pentane under N2, stirring at room temp, the react. was complete within about 1 h; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), elem. anal., (the org. products identified by GC and NMR);
参考文献
Organometallics, , vol. 8, p. 2225 - 2232
反应条件
aluminum oxide; {4-OK-C6H2-2,6-[OP(t-Bu)2]2}Ir(C2H4) 39.9667 h; Heating; Product distribution / selectivity;
参考文献
WO2008/153869 A2, ;
Page/Page column 19-20 ;
参考文献
Nippon Kagaku Kaishi, vol. 64, p. 1091
Chem. Zentralbl., , vol. 118, p. 3756
参考文献
Journal of the American Chemical Society, , vol. 77, p. 357
Journal of the American Chemical Society, , vol. 81, p. 651,654
反应条件
Ni(PPh3)n - Et3Al2Cl3 (n=2-4) in n-heptane T=40 - 60°C; P=750.06 - 11250.9 Torr; selectivity , other Ni-Ligands Bu3PO, (BuO)2PNEt2, Ni(CO)x(PPh3)y/Al2O3, catalytic properties;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 39, # 3.1 p. 444 - 447
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 3 p. 512 - 516
反应条件
lt;Mo(NO)2(MeCN)4gt;(BF4)2 in nitromethane T=0°C; 6 h; catalytic ring opening; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 567 - 588
参考文献
US2404927 , ;
Journal of the American Chemical Society, , vol. 66, p. 1423
反应条件
2,6-dimethylpyridine in methanol T=70.1°C; 1104 h; other reaction time; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 45, # 12 p. 2506 - 2507
反应条件
hydrogen; zirconium oxide T=156.9°C; variation of temperature; deuterium labelling experiments; activation energy, frequency factor; KineticsMechanism;
参考文献
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, , vol. 83, # 9 p. 3069 - 3082