2-辛基-1,3-二氧戊环合成路线 （共 14 条）
反应条件
sulfuric acid 10 h; Ambient temperature;
参考文献
Iwamoto, Minoru; Kubota, Noboru; Takagi, Yoshikazu; Kogami, Kunio; Hayashi, Kazuo
Agricultural and Biological Chemistry, 1982 , vol. 46, # 9 p. 2383 - 2386
参考文献
Rosenthal,I.; Elad,D.
Journal of Organic Chemistry, 1968 , vol. 33, p. 805 - 811
反应条件
[bis(acetoxy)iodo]benzene; water; lithium bromide T=20°C; 0.25 h;
参考文献
Panchan, Waraporn; Chiampanichayakul, Supanimit; Snyder, Deanna L.; Yodbuntung, Siriporn; Pohmakotr, Manat; Reutrakul, Vichai; Jaipetch, Thaworn; Kuhakarn, Chutima
Tetrahedron, 2010 , vol. 66, # 14 p. 2732 - 2735
反应条件
tri-ruthenium(0)dodecacarbonyl; tetraethylammonium chloride; hydrogen; acetic acid
T=140°C; P=15001.5 Torr; 20 h; Ionic liquidAutoclaveInert atmosphere; Overall yield = 36 percent; Overall yield = 87 percentChromat.; regioselective reaction;
参考文献
Norinder, Jakob; Rodrigues, Claudia; Boerner, Armin
Journal of Molecular Catalysis A: Chemical, 2014 , vol. 391, # 1 p. 139 - 143
反应条件
chloro-trimethyl-silane in dichloromethane
48 h; Heating;
参考文献
Chan, T. H.; Brook, Michael A.; Chaly, T.
Synthesis, 1983 , # 3 p. 203 - 205
反应条件
tetraethylammonium p-toluenesulfonate in acetonitrile
carbon rod anode, carbon rod cathode (i.d. 2 mm); constant current: 10 mA; electricity 4.16 F/mol;
参考文献
Yoshida, Jun-ichi; Isoe, Sachihiko
Chemistry Letters, 1987 , p. 631 - 634
反应条件
tri-ruthenium(0)dodecacarbonyl; tetraethylammonium chloride; hydrogen; toluene-4-sulfonic acid
T=140°C; P=15001.5 Torr; 20 h; Ionic liquid; regioselective reaction;
参考文献
Norinder, Jakob; Rodrigues, Claudia; Boerner, Armin
Journal of Molecular Catalysis A: Chemical, 2014 , vol. 391, # 1 p. 139 - 143
反应条件
[Rh(acac)2(CO)2]; BF4(1-)*C20H18NO2P*H(1+); hydrogen; 1-n-butyl-3-methylimidazolium tetrafluoroborate
T=80°C; P=37503.8 Torr; 2 h; AutoclaveGreen chemistry;
参考文献
Jin, Xin; Zhao, Kun; Cui, Feifei; Kong, Fangfang; Liu, Qiangqiang
Green Chemistry, 2013 , vol. 15, # 11 p. 3236 - 3242
反应条件
1: 92 percent / NaI, 18-crown-6 / toluene; dimethylsulfoxide / 6 h / 90 - 100 °C
2: 1.) Mg, 2.) Li2CuCl4 / 1.) THF, 2.) r.t., 1 h
View Scheme
参考文献
Iwamoto, Minoru; Kubota, Noboru; Takagi, Yoshikazu; Kogami, Kunio; Hayashi, Kazuo
Agricultural and Biological Chemistry, 1982 , vol. 46, # 9 p. 2383 - 2386
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene
T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
