3,3-二甲基-2-丁醇合成路线 （共 125 条）
反应条件
potassium tert-butylate; hydrogen; [ruthenium(dichloride)(Ph2PC2H4NH2)2] T=20°C; P=2280 Torr; 12 h;
参考文献
Rautenstrauch, Valentin; Churlaud, Raphael; Morris, Robert Harold; Abdur-Rashid, Kamaluddin
Patent: US2004/15017 A1, 2004 ;
Location in patent: Page 5 ;
反应条件
1: With Yb(OAc)3 in tetrahydrofuran; methanol T=50°C; 4 h; 2: With hydrogen; platinum on activated charcoal in tetrahydrofuran; methanol T=50°C; P=6205.94 Torr; 20 h;
参考文献
JACOBS UNIVERSITY BREMEN GGMBH
Patent: WO2007/104359 A1, 2007 ;
Location in patent: Page/Page column 25-26 ;
反应条件
DBTO Ambient temperatureIrradiation; Yield given. Yields of byproduct given;
参考文献
Suslick, Kenneth; Cook, Bruce; Fox, Mary
Journal of the Chemical Society, Chemical Communications, 1985 , # 9 p. 580 - 582
反应条件
titanium tetrachloride; zinc in tetrahydrofuran T=65°C; 48 h;
参考文献
Hellmann, Goetz; Hellmann, Siegried; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Chemische Berichte, 1982 , vol. 115, # 10 p. 3364 - 3383
反应条件
mercury(II) diacetate in tetrahydrofuran; water 1 h; Ambient temperatureother mercuri salts, other reaction time; Product distribution;
参考文献
Morrill, Terence C.; D'Souza, Christopher A.; Yang, Lu; Sampognaro, Anthony J.
Journal of Organic Chemistry, 2002 , vol. 67, # 8 p. 2481 - 2484
反应条件
potassium tert-butylate in water; dimethyl sulfoxide 48 h; Ambient temperature;
参考文献
Larson, Gerald L.; Prieto, J. Antonio; Ortiz, Edgardo
Tetrahedron, 1988 , vol. 44, # 13 p. 3781 - 3790
参考文献
Aldrich-Boranes, Inc.
Patent: US4772752 A1, 1988 ;
参考文献
Normant
Bulletin de la Societe Chimique de France, 1957 , p. 1444
Full Text Show Details
Lewis; Wright
Journal of the American Chemical Society, 1952 , vol. 74, p. 1257
反应条件
in diethyl ether T=-25°C; 15 h;
参考文献
Weidmann, Beat; Seebach, Dieter
Helvetica Chimica Acta, 1980 , vol. 63, # 8 p. 2451 - 2454
反应条件
1: H2 / rhodium cationic complex with (R)-1-<(S)-1',2-bis(diphenylphosphino)ferrocenyl>ethanol <(R)-(S)-BPPFOH> / benzene / 70 h / 30 °C / 38000 Torr 2: 1.) MeLi 2.) H3O(1+) / 1.) ether View Scheme
参考文献
Hayashi, Tamio; Kanehira, Koichi; Kumada, Makoto
Tetrahedron Letters, 1981 , vol. 22, # 44 p. 4417 - 4420
