6-甲基-5-庚烯-2-醇合成路线 （共 96 条）
反应条件
reusable unsupported rhenium nanocrystalline particle in neat (no solvent) T=180°C; 10 h; Green chemistry;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 3 p. 833 - 836
Angew. Chem., , vol. 126, # 03 p. 852 - 855,4
反应条件
D-glucose; Yarrowia lipolytica YL10; peptone in N,N-dimethyl-formamide T=28°C; Oxidation; 72 h; Microbiological reaction; Title compound not separated from byproducts;
参考文献
Fantin, Giancarlo; Fogagnolo, Marco; Medici, Alessandro; Pedrini, Paola; Fontana, Silvia
Tetrahedron Asymmetry, 2000 , vol. 11, # 11 p. 2367 - 2373
反应条件
sodium hydrogencarbonate in tetrachloromethane 24 h; Heating;
参考文献
Monatshefte fur Chemie, , vol. 131, # 10 p. 1091 - 1096
反应条件
whole cells of Rhodococcus ruber DSM 44541; acetone in phosphate buffer T=24°C; Oppenauer oxidation; pH=8.0;
参考文献
Stampfer, Wolfgang; Kosjek, Birgit; Faber, Kurt; Kroutil, Wolfgang
Journal of Organic Chemistry, 2003 , vol. 68, # 2 p. 402 - 406
反应条件
1: 42 percent / PBr3, pyridine / diethyl ether 2: 60 percent / dimethylsulfoxide 3: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 4: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 5: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 6: 82 percent / diethyl ether / Ambient temperature 7: 17 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
(cetyl)Me3N(1+)MnO4(1-) in dichloromethane T=25°C; 3.5 h;
参考文献
Tetrahedron Letters, , vol. 27, # 34 p. 4079 - 4082
反应条件
alcohol dehydrogenase from Lactobacillus kefir; alcohol dehydrogenase from Rhodococcus ruber DSM 44541; YcnD-oxidoreductase T=30°C; pH=7.5; 3 h; aq. bufferResolution of racemateEnzymatic reaction; optical yield given as percent eeenantiospecific reaction;
参考文献
Voss, Constance V.; Gruber, Christian C.; Faber, Kurt; Knaus, Tanja; Macheroux, Peter; Kroutil, Wolfgang
Journal of the American Chemical Society, 2008 , vol. 130, # 42 p. 13969 - 13972
反应条件
Candida antarctica lipase B; (η5-C5Ph5)Ru(CO)2Cl; potassium tert-butylate; sodium carbonate in tetrahydrofuran; toluene T=20°C; 72 h;
参考文献
Martin-Matute, Belen; Edin, Michaela; Bogar, Krisztian; Kaynak, F. Betuel; Baeckvall, Jan-E.
Journal of the American Chemical Society, 2005 , vol. 127, # 24 p. 8817 - 8825
反应条件
Rhodococcus erythropolis DSM 43066 cells; alcohol dehydrogenase from Lactobacillus kefir; glucose dehydrogenase BS; D-glucose; nicotinamide adenine dinucleotide in alkaline aq. solution T=30°C; pH=7.5; 16 h; Title compound not separated from byproducts.;
参考文献
Voss, Constance V.; Gruber, Christian C.; Kroutil, Wolfgang
Angewandte Chemie - International Edition, 2008 , vol. 47, # 4 p. 741 - 745
反应条件
alcohol dehydrogenase from Lactobacillus kefir; YcnD-oxidoreductase; NADPH T=30°C; pH=7.5; 6 h; aq. bufferEnzymatic reaction; optical yield given as percent eeenantiospecific reaction;
参考文献
Voss, Constance V.; Gruber, Christian C.; Faber, Kurt; Knaus, Tanja; Macheroux, Peter; Kroutil, Wolfgang
Journal of the American Chemical Society, 2008 , vol. 130, # 42 p. 13969 - 13972
