1,4-双(三甲硅基)-1,3-丁二炔合成路线 （共 93 条）
反应条件
oxygen in hexane T=20°C;
参考文献
Szesni, Normen; Kaiser, Melanie; Putzien, Sophie; Fischer, Richard W.
Combinatorial Chemistry and High Throughput Screening, 2012 , vol. 15, # 2 p. 170 - 179
反应条件
2,2,6,6-tetramethyl-1-piperidinyloxy, free radical in tetrahydrofuran T=0 - 66°C; 7 h; Inert atmosphere;
参考文献
Maji, Modhu Sudan; Pfeifer, Thorben; Studer, Armido
Angewandte Chemie - International Edition, 2008 , vol. 47, # 49 p. 9547 - 9550
反应条件
1: 1,1,2,3,4,4-hexachloro-1,3-butadiene With n-butyllithium in tetrahydrofuran; hexane T=-78 - 20°C; 2.75 h; Inert atmosphere; 2: chloro-trimethyl-silane in tetrahydrofuran; hexane T=0 - 20°C; 1.75 h; Inert atmosphere;
参考文献
Drew, Samuel L.; Lawrence, Andrew L.; Sherburn, Michael S.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 15 p. 4221 - 4224
Angew. Chem., 2013 , vol. 125, # 15 p. 4315 - 4318,4
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere;
参考文献
Angewandte Chemie, International Edition, , vol. 48, # 36 p. 6731 - 6734
反应条件
boron trifluoride diethyl etherate; difluoro[4-(trifluoromethyl)phenyl]-λ(3)-bromane in dichloromethane T=-78 - 20°C; 5 h;
参考文献
Ochiai, Masahito; Nishi, Yoshio; Goto, Satoru; Frohn, Hermann J.
Angewandte Chemie - International Edition, 2005 , vol. 44, # 3 p. 406 - 409
反应条件
n-butyllithium in tetrahydrofuran; hexane 1.) -25 deg C to -20 deg C, 1 h; 2.) 25 deg C, 1 h;
参考文献
Zweifel, George; Rajagopalan, Shyamala
Journal of the American Chemical Society, 1985 , vol. 107, # 3 p. 700 - 701
反应条件
copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=20°C; 16 h;
参考文献
Plater, M. John; Aiken, Stuart; Bourhill, Grant
Tetrahedron Letters, 2001 , vol. 42, # 11 p. 2225 - 2229
反应条件
copper(l) iodide; 1,2-dichloro-4,5-diiodobenzene; triethylamine; triphenylphosphine; bis(benzonitrile)palladium(II) dichloride 1.) 10 h; 2.) 1 h, 85 deg C;
参考文献
Journal of the American Chemical Society, , vol. 107, p. 5670
反应条件
n-butyllithium in tetrahydrofuran; hexane 1.) -40 deg C to -45 deg C, 30 min; 2.) 25 deg C, 1 h;
参考文献
Zweifel, George; Rajagopalan, Shyamala
Journal of the American Chemical Society, 1985 , vol. 107, # 3 p. 700 - 701
反应条件
copper(l) iodide; triethylamine; triphenylphosphine; bis(benzonitrile)palladium(II) dichloride 1.) 10 h; 2.) 1 h, 85 deg C;
参考文献
Journal of the American Chemical Society, , vol. 107, p. 5670
