(三甲基硅基)乙酸乙酯合成路线 （共 118 条）
反应条件
boron trifluoride diethyl etherate 1.)ethyl trimethylsilylacetate, ether, -78 grad C, warmed to rt., stirred overnight, 2.) BF3OEt2, CH2Cl2, 2 h, rt.; Yield given. Multistep reaction;
参考文献
Larson, Gerald L.; Hernandez, David
Tetrahedron Letters, 1982 , vol. 23, # 10 p. 1035 - 1038
反应条件
boron trifluoride diethyl etherate 1.)ethyl trimethylsilylacetate, ether, -78 grad C, warmed to rt., stirred overnight, 2.) BF3OEt2, CH2Cl2, 2 h, rt.; Yield given. Multistep reaction;
参考文献
Larson, Gerald L.; Hernandez, David
Tetrahedron Letters, 1982 , vol. 23, # 10 p. 1035 - 1038
反应条件
lithium diisopropyl amide 1.) THF, hexane, -78 deg C, 1 h, 2.) a) from -78 deg C to room temp., 1 h, b) room temp., 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tsuge, Otohiko; Sone, Kazuhiro; Urano, Satoshi; Matsuda, Koyo
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5171 - 5177
反应条件
lithium diisopropyl amide 1.) THF, hexane, -78 deg C, 1 h, 2.) a) from -78 deg C to room temp., 1 h, b) room temp., 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tsuge, Otohiko; Sone, Kazuhiro; Urano, Satoshi; Matsuda, Koyo
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5171 - 5177
反应条件
lithium diisopropyl amide 1.) THF, hexane, -78 deg C, 1 h, 2.) a) from -78 deg C to room temp., 1 h, b) room temp., 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tsuge, Otohiko; Sone, Kazuhiro; Urano, Satoshi; Matsuda, Koyo
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5171 - 5177
反应条件
t-Bu-N=P[N=P(NMe2)3]3 in tetrahydrofuran; hexane T=-78°C; Peterson olefination; 6 h;
参考文献
Kobayashi, Koji; Ueno, Masahiro; Kondo, Yoshinori
Chemical Communications, 2006 , # 29 p. 3128 - 3130
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; magnesium bromide; lithium diisopropyl amide in tetrahydrofuran T=0°C; 0.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Larcheveque, Marc; Debal, Alain
Journal of the Chemical Society, Chemical Communications, 1981 , # 17 p. 877 - 878
反应条件
1: With C{N(2,6-iPr2C6H3)CH}2 in N,N-dimethyl-formamide T=0 - 20°C; Reformatsky Reaction; 24 h; Inert atmosphereGreen chemistry; 2: With hydrogenchloride in water; N,N-dimethyl-formamide Reformatsky Reaction; 0.5 h; Inert atmosphereGreen chemistry;
参考文献
Zou, Xiao-Lei; Du, Guang-Fen; Sun, Wan-Fu; He, Lin; Ma, Xiao-Wei; Gu, Cheng-Zhi; Dai, Bin
Tetrahedron, 2013 , vol. 69, # 2 p. 607 - 612
参考文献
Gold; Sommer; Whitmore
Journal of the American Chemical Society, 1948 , vol. 70, p. 2875
参考文献
Gold; Sommer; Whitmore
Journal of the American Chemical Society, 1948 , vol. 70, p. 2874
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Gmelin Handbook: Si: MVol.C, 4, page 14 - 18
