反应条件
1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; Negishi coupling reaction; 0.166667 h; Inert atmosphere;
2: With zinc(II) chloride in tetrahydrofuran; hexane
T=-78 - 20°C; Negishi coupling reaction; Inert atmosphere;
3: 2,4,6-trimethylphenyl iodide With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran; hexane
T=60°C; Negishi coupling reaction; 2 h; Inert atmosphere;
参考文献
Liu, Qiang; Lan, Yu; Liu, Jing; Li, Gang; Wu, Yun-Dong; Lei, Aiwen
Journal of the American Chemical Society, 2009 , vol. 131, # 29 p. 10201 - 10210
