1-三甲基硅烷-1-己炔合成路线 （共 85 条）
反应条件
NiCl{C6H3-2,6-(OPPh2)2} in tetrahydrofuran; 1-methyl-pyrrolidin-2-one; hexane T=20°C; 0.75 h; Inert atmosphere;
参考文献
Xu, Guoqiang; Li, Xiaoyan; Sun, Hongjian
Journal of Organometallic Chemistry, 2011 , vol. 696, # 18 p. 3011 - 3014
反应条件
NiCl{C6H3-2,6-(OPPh2)2} in tetrahydrofuran; 1-methyl-pyrrolidin-2-one; hexane T=20°C; 0.75 h; Inert atmosphere;
参考文献
Xu, Guoqiang; Li, Xiaoyan; Sun, Hongjian
Journal of Organometallic Chemistry, 2011 , vol. 696, # 18 p. 3011 - 3014
反应条件
NiCl{C6H3-2,6-(OPPh2)2} in tetrahydrofuran; 1-methyl-pyrrolidin-2-one; hexane T=20°C; 0.75 h; Inert atmosphere;
参考文献
Xu, Guoqiang; Li, Xiaoyan; Sun, Hongjian
Journal of Organometallic Chemistry, 2011 , vol. 696, # 18 p. 3011 - 3014
反应条件
1: hex-1-yne With n-butyllithium in tetrahydrofuran T=-78 - 0°C; 1.33333 h; Inert atmosphere; 2: chloro-trimethyl-silane in tetrahydrofuran T=-78 - 20°C; 2 h; Inert atmosphere;
参考文献
Nion, Aymeric; Katsonis, Nathalie; Marchenko, Alexandre; Aubert, Corinne; Fichou, Denis
New Journal of Chemistry, 2013 , vol. 37, # 8 p. 2261 - 2265
反应条件
in not given in presence of CuCl2;;
参考文献
Frisch, K. C.; Young, R. B.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4853 - 4856
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Gmelin Handbook: Si: MVol.C, 16, page 48 - 53
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General Electric Co.
Patent: US2671795 , 1954 ;
C. A., 1955 , p. 3241
参考文献
Voronkov, M. G.; Dubinskaya, E. I.; Putilova, G. G.; Larin, M. F.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 4 p. 678
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 4 p. 897
反应条件
in tetrahydrofuran T=-20°C;
参考文献
Mai, Khuong; Patil, Ghanshyam
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3545 - 3548
反应条件
1-methyl-pyrrolidin-2-one; copper dichloride in tetrahydrofuran T=0°C; 1.25 h; Inert atmosphere; chemoselective reaction;
参考文献
Cahiez, Gerard; Gager, Olivier; Buendia, Julien
Angewandte Chemie - International Edition, 2010 , vol. 49, # 7 p. 1278 - 1281
反应条件
dihydrogen hexachloroplatinate; iodine in hexane T=20°C; 2 h;
参考文献
Voronkov, M. G.; Pukhnarevich, V. B.; Ushakova, N. I.; Tsykhanskaya, I. I.; Albanov, A. I.; Vitkovskii, V. Yu.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 1 p. 94 - 100,80 - 85
反应条件
sodium in dimethyl sulfoxide T=90 - 95°C; 12 h;
参考文献
Calas,R.; Bourgeois,P.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1969 , vol. 268, p. 72 - 74
