1: H2SO4 2: 82 percent / PPh3, imidazole, I2 / toluene / 0.25 h / Heating 3: 91 percent / NaH / hexamethylphosphoric acid triamide / 2 h / Ambient temperature 4: 83 percent / Hg(OAc)2 / acetone; H2O / 0.25 h / 0 °C 5: 73 percent / DMAP / pyridine / 4 h / Ambient temperature 6: 95 percent / CeCl3*7H2O, NaBH4 / methanol / 0.67 h / -78 °C 7: 20 percent / DMAP / pyridine / 6 h / Ambient temperature 8: 1.) NaOMe, 2.) conc. HCl / 1.) methanol, room temperature, 15 min, 2.) room temperature, 15 min View Scheme
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