1,1'-(1,2-乙炔二基)二(4-甲基苯)合成路线 （共 99 条）
反应条件
piperidine; caesium carbonate; [(P{(C6H11)3})2Pd(Cl)2] in dimethyl sulfoxide
T=120°C; Sonogashira coupling; 12 h;
参考文献
Yi, Chenyi; Hua, Ruimao; Zeng, Hanxiang; Huang, Qiufeng
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 10 p. 1738 - 1742
反应条件
sodium perchlorate; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 4-BzO-TEMPO in water; acetonitrile
T=20°C; Inert atmosphereElectrochemical reaction;
参考文献
Mitsudo, Koichi; Shiraga, Takuya; Mizukawa, Jun-Ichi; Suga, Seiji; Tanaka, Hideo
Chemical Communications, 2010 , vol. 46, # 48 p. 9256 - 9258
反应条件
copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine in 1,4-dioxane; water
T=80°C; Sonogashira coupling; 12 h;
参考文献
Yum, Eul Kgun; Son, Jong Woo; Kim, Soo Kwang; Kim, Sung Nam; Kim, Kyung Mahn; Lee, Chul Wee
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 7 p. 2097 - 2099
反应条件
oxygen; cobalt(II)salen in methanol; benzene
2 h; Ambient temperature;
参考文献
Inada, Akira; Nakamura, Yushin; Morita, Yutaka
Chemical & Pharmaceutical Bulletin, 1982 , vol. 30, # 3 p. 1041 - 1042
反应条件
1: Sb(o-tolyl)3 With [bis(acetoxy)iodo]benzene in dichloromethane
T=20°C; 7 h;
2: bis(trimethylsilyl)-acetylene With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(l) iodide in acetonitrile
T=50°C; 5 h; Further stages.;
参考文献
Kang, Suk-Ku; Ryu, Hyung-Chul; Hong, Young-Taek
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 7 p. 736 - 739
反应条件
t-Bu2P(biphenyl); tetrabutyl ammonium fluoride; tris-(dibenzylideneacetone)dipalladium(0) in tetrahydrofuran
T=20°C; 24 h;
参考文献
Faller, Jack W.; Kultyshev, Roman G.; Parr, Jonathan
Tetrahedron Letters, 2003 , vol. 44, # 3 p. 451 - 453
反应条件
bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide
T=80°C; 3 h;
参考文献
Park, Kyungho; Bae, Goun; Moon, Jeongju; Choe, Jaehoon; Song, Kwang Ho; Lee, Sunwoo
Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6244 - 6251
反应条件
bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide
T=110°C; 3 h;
参考文献
Park, Kyungho; Bae, Goun; Moon, Jeongju; Choe, Jaehoon; Song, Kwang Ho; Lee, Sunwoo
Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6244 - 6251
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; ytterbium in tetrahydrofuran
T=-10°C; 0.333333 h;
参考文献
Taniguchi, Yuki; Fujii, Nobuto; Makioka, Yoshikazu; Takaki, Ken; Fujiwara, Yuzo
Chemistry Letters, 1993 , # 7 p. 1165 - 1168
反应条件
hexacarbonyl molybdenum; 4-chloro-phenol in various solvent(s)
T=140°C;
参考文献
Pschirer, Neil Gregory; Bunz, Uwe H. F.
Tetrahedron Letters, 1999 , vol. 40, # 13 p. 2481 - 2484
