1: With n-butyllithium; tri-n-butyl-tin hydride; diisopropylamine in tetrahydrofuran; hexane T=-78°C; 0.5 h; 2: tri-n-butyl-tin hydride in tetrahydrofuran; hexane T=-78 - 0°C; 0.5 h; 3: chloromethyl methyl ether With water more than 3 stages;
in tetrahydrofuran soln. of lithium tributylstannate cooled to 0°C, added ClCH2OCH3in THF, stirred at ambient temp. for 12 h; flash chromy., elem. anal.;
参考文献
Labadie,J.W.; Stille,J.K.
Journal of the American Chemical Society, 1983 , vol. 105, p. 6129
1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; 2: With tri-isopropoxy-borane in tetrahydrofuran; hexane T=-78 - 20°C; 0.333333 h; 3: With potassium hydrogen difluoride in tetrahydrofuran; hexane T=0°C;
