Noeth, Heinrich; Warchhold, Marcus
European Journal of Inorganic Chemistry, 2004 , # 5 p. 1115 - 1124
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反应条件
in hexane; toluene byproducts: LiBr; hexane soln. of Li-compd. was added to toluene soln. of Br-compd.; LiBr was filtered off, soln. was cooled to -30 °C, catecholatoborane was sepd., Me3SnBH2 was detected by (11)B NMR;
参考文献
Habereder, Tassilo; Noeth, Heinrich
Zeitschrift fur Anorganische und Allgemeine Chemie, 2001 , vol. 627, # 4 p. 789 - 796
[Mo(H)(Cl)(P(CH3)3)3(N(C6H3(CH3CHCH3)2))] in benzene-d6 react. of HBCat with 0.4 M soln. of 3-hexyne (1:1 molar ratio) in C6D6 at temp. of 22°C for 24 h in presence of 5 molpercent of Mo complex as catalyst; detd. by NMR;
参考文献
Khalimon, Andrey Y.; Farha, Philip; Kuzmina, Lyudmila G.; Nikonov, Georgii I.
Chemical Communications, 2012 , vol. 48, # 3 p. 455 - 457
Rh catalyst in benzene-d6 1 h; Title compound not separated from byproducts;
参考文献
Vogels, Christopher M.; O'Connor, Paul E.; Phillips, Trevor E.; Watson, Keith J.; Shaver, Michael P.; Hayes, Paul G.; Westcott, Stephen A.
Canadian Journal of Chemistry, 2001 , vol. 79, # 12 p. 1898 - 1905
1: With (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; [Rh(COD)2](1+)*BF4(1-) in ethylene glycol dimethyl ether T=-78 - 20°C; 2: With sodium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether T=0 - 20°C; 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Journal of Fluorine Chemistry, , vol. 128, # 7 p. 827 - 831
1: With [Rh(COD)(dppb)](1+)*BF4(1-) in tetrahydrofuran T=-25°C; 0.75 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
