2-苯基-1,2-环氧丙烷合成路线 (共 116 条)
反应条件
methyllithium; lithium bromide in tetrahydrofuran; diethyl ether T=-78 - 20°C;
参考文献
Sadhu, Kizhakethil Mathew; Matteson, Donald S.
Tetrahedron Letters, 1986 , vol. 27, # 7 p. 795 - 798
反应条件
Oxonereg;; sodium hydrogencarbonate; ruthenium in water; acetonitrile T=20°C; 2 h;
参考文献
Angewandte Chemie - International Edition, , vol. 43, # 25 p. 3303 - 3307
反应条件
caesium carbonate in tetrahydrofuran T=80°C; 12 h;
参考文献
Forbes, David C.; Bettigeri, Sampada V.; Patrawala, Samit A.; Pischek, Susanna C.; Standen, Michael C.
Tetrahedron, 2009 , vol. 65, # 1 p. 70 - 76
反应条件
potassium hydroxide in diethyl ether; pentane 0.666667 h; Ambient temperature;
参考文献
Sanseverino, Antonio Manzolillo; De Mattos, Marcio C. S.
Synthetic Communications, 1998 , vol. 28, # 3 p. 559 - 572
反应条件
sodium hydroxide in dichloromethane T=50°C; 15 h;
参考文献
Mosset, Paul; Gree, Rene
Synthetic Communications, 1985 , vol. 15, # 8 p. 749 - 758
反应条件
sodium chlorite; (ethylenedinitrilo)tetraacetic acid disodium salt in water; acetonitrile T=55 - 65°C; 17 h;
参考文献
Journal of Organic Chemistry, , vol. 70, # 23 p. 9610 - 9613
反应条件
1: With tetramethylene sulfide; styrene; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine in dichloromethane T=20°C; Corey-Chaykovsky reaction; Inert atmosphere; 2: With 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-25,45-catenodi(phosphazene) in tetrahydrofuran; dichloromethane T=20°C; Corey-Chaykovsky reaction; Inert atmosphere;
参考文献
Kavanagh, Sarah A.; Piccinini, Alessandro; Connon, Stephen J.
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 2089 - 2093
反应条件
oxygen; α-ketophenylacetic acid in benzene T=20°C; Irradiation; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 103, # 21 p. 6455 - 6460
反应条件
in dimethyl sulfoxide T=20°C; Addition; 12.5 h;
参考文献
Cleij; Archelas; Furstoss
Journal of Organic Chemistry, 1999 , vol. 64, # 14 p. 5029 - 5035
反应条件
oxygen; isopropenylbenzene in benzene T=20°C; Irradiation; Further byproducts given. Yields of byproduct given;
参考文献
Sawaki, Yasuhiko; Ogata, Yoshiro
Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6455 - 6460