(R)-(-)-扁桃酸甲酯合成路线 (共 107 条)
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
(DHQD)2PHAL; methanesulfonamide; α-AD mix {K4[Fe(CN)6], OsO4, Na2CO3, (DHQ)2-PHAL} in water; tert-butyl alcohol T=0°C; Oxidation; Sharpless asymmetric dihydroxylation; 6 h; Title compound not separated from byproducts;
参考文献
Chemistry - A European Journal, , vol. 5, # 8 p. 2270 - 2280
反应条件
1: CH2Cl2 / 20 °C 2: aq. cerium ammonium nitrate / acetonitrile / 0 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 128, # 6 p. 1810 - 1811
反应条件
1: benzoylquinidine; N,N-diisopropylethylamine / tetrahydrofuran / -78 °C 2: CH2Cl2 / 20 °C 3: aq. cerium ammonium nitrate / acetonitrile / 0 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 128, # 6 p. 1810 - 1811
反应条件
1: Mg(ClO4)2 / 96 h 2: methanol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 109, # 10 p. 3155 - 3156
反应条件
methanol; yeast lipase in di-isopropyl ether T=30°C; 552 h;
参考文献
Journal of Organic Chemistry, , vol. 54, # 10 p. 2453 - 2455
反应条件
hydrogenchloride in diethyl ether
参考文献
Noe, Christian R.
Chemische Berichte, 1982 , vol. 115, # 4 p. 1591 - 1606
反应条件
methanesulfonamide; β-AD-Mix; 1,4-bis(9-O-dihydroquinidine)phthalazine in water; tert-butyl alcohol T=0°C; Oxidation; Sharpless asymmetric dihydroxylation; 6 h; Title compound not separated from byproducts;
参考文献
Chemistry - A European Journal, , vol. 5, # 8 p. 2270 - 2280
反应条件
1: With ozone T=-78°C; 2: With dimethylsulfide in methanol T=-78 - 20°C; Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 6, # 5 p. 727 - 729
反应条件
1: Nocardia diaphanozonaria cells; glycerol; peptone / beef extract; yeast extract / H2O / 48 h / 30 °C / pH 7.0 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 68, # 19 p. 7234 - 7242