3-乙氧基-2-甲基-2-环己烯-1-酮合成路线 （共 10 条）
反应条件
1: 76 percent / O3 / methanol / -70 °C 2: aq. KOH / ethanol / 2 h / Heating View Scheme
参考文献
Sugiyama, Tomohito; Yamakoshi, Hideyuki; Nojima, Masatomo
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4211 - 4218
反应条件
ozone in methanol T=-70°C;
参考文献
Sugiyama, Tomohito; Yamakoshi, Hideyuki; Nojima, Masatomo
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4211 - 4218
反应条件
toluene-4-sulfonic acid in toluene
Heating / reflux;
参考文献
MEIJI DAIRIES CORPORATION
Patent: WO2004/87630 A1, 2004 ;
Location in patent: Page 7-8 ;
反应条件
tert.-butylnitrite; 3 A molecular sieve in dichloromethane
T=80°C; 36 h;
参考文献
Suzuki, Masumi; Sugai, Takeshi
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 6 p. 1217 - 1228
反应条件
sodium hydride
1.) THF, 2.) destill., 0.013kPa; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Garst, Michael E.; McBride, Bill J.
Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1362 - 1364
参考文献
Meek et al.
Journal of the Chemical Society, 1953 , p. 811,813
反应条件
1: potassium ethylate
2: methanol. sodium methylate
View Scheme
参考文献
Meek et al.
Journal of the Chemical Society, 1953 , p. 811,813
反应条件
sodium hydride
1.) THF, 2.) C8H10, 24 h, reflux; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Garst, Michael E.; McBride, Bill J.
Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1362 - 1364
反应条件
ethanol; sulfuric acid
参考文献
Meek et al.
Journal of the Chemical Society, 1953 , p. 811,813
反应条件
1: 1.) Mg, dibromoethane / 1.) THF, RT, 2 h, 2.) THF, RT, 15 h
2: 0.738 g / oxalic acid / methanol / 6 h / Ambient temperature
3: 1.068 g / Et3N / tetrahydrofuran / 2 h / Ambient temperature
4: 997 mg / LiBr / tetrahydrofuran / 15 h / Ambient temperature
View Scheme
参考文献
Sha, Chin-Kang; Ouyang, Sheng-Lian; Hsieh, Der-Yung; Chang, Ruei-Chih; Chang, Shang-Chia
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1490 - 1494
