[二氯(乙氧基)甲基]硅烷合成路线 （共 13 条）
反应条件
methyltrichloromonosilane; triethylamine in toluene T=0 - 100°C; 1.66667 - 1.83333 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPNAY
Patent: US2009/143608 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
Marko catalyst in toluene T=40 - 60°C; 16 h; Overall yield = 97 percentSpectr.;
参考文献
Gigler, Peter; Drees, Markus; Riener, Korbinian; Bechlars, Bettina; Herrmann, Wolfgang A.; Kuehn, Fritz E.
Journal of Catalysis, 2012 , vol. 295, p. 1 - 14
参考文献
Brune,H.A.
Chemische Berichte, 1964 , vol. 97, p. 2829 - 2847
反应条件
CH3SiCl3 and CH3Si(OC2H5)3 (1:2 mol) at 180°C;;
参考文献
Kumada, M.
J. Inst. Polytechn. Osaka Univ. C, 1952 , vol. 2, p. 139 - 146
C. A., 1954 , p. 11303
Full Text Show Details
Gmelin Handbook: Si: MVol.C, 72, page 200 - 203
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Tagachenkov, A. A.; Bykovchenko, V. G.
Russian Journal of General Chemistry, 1995 , vol. 65, # 2.2 p. 241 - 243
Zhurnal Obshchei Khimii, 1995 , vol. 65, # 2 p. 281 - 284
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Tagachenkov, A. A.; Bykovchenko, V. G.
Russian Journal of General Chemistry, 1995 , vol. 65, # 2.2 p. 241 - 243
Zhurnal Obshchei Khimii, 1995 , vol. 65, # 2 p. 281 - 284
反应条件
in toluene T=61 - 62°C; 0.316667 - 0.35 h; Product distribution / selectivity;
参考文献
DOW CORNING CORPORATION
Patent: WO2006/83665 A1, 2006 ;
Location in patent: Page/Page column 5-7 ;
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide 24 h; other chloro- and alkoxysilanes, also in absence of catalyst, also in toluene as solvent; Product distribution;
参考文献
Nilolaev, G. A.; Mileshkevich, V. P.; Vainshtein, P. M.; Shmeleva, O. A.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 9 p. 2098 - 2101,1867 - 1870
反应条件
N,N-dimethyl-formamide T=90°C; 5.5 h; ΔG0, ΔH0; Product distributionThermodynamic dataEquilibrium constant;
参考文献
Kopylov, V. M.; Shragin, I. S.; Rybkina, T. I.; Chernyshev, A. I.; Shkol'nik, M. I.; Ukhina, E. N.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 2 p. 359 - 366,321 - 327
反应条件
in toluene equilibrium composition; Product distribution;
参考文献
Kopylov, V. M.; Shragin, I. S.; Ukhina, E. N.; Shkol'nik, M. I.; Chernyshev, A. I.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 5 p. 1074 - 1080,957 - 962
