乙基三(三甲基硅烷基)原硅酸盐合成路线 （共 7 条）
反应条件
1: bis-trimethylsilyl ether With sulfuric acid T=0 - 10°C; 0.5 h; 2: ethyl orthosilicate T=10°C; 1.75 h; 3: With water T=5 - 50°C; 4 h;
参考文献
Kanebo Cosmetics, Inc.; Shin-Etsu Chemical Co., Ltd.
Patent: EP1607081 A1, 2005 ;
Location in patent: Page/Page column 14-16 ;
反应条件
1: ethanol; bis-trimethylsilyl ether T=0 - 10°C; 2: With trifluorormethanesulfonic acid T=10°C; 0.5 h; 3: ethyl orthosilicate With water more than 3 stages;
参考文献
Kanebo Cosmetics, Inc.; Shin-Etsu Chemical Co., Ltd.
Patent: EP1607081 A1, 2005 ;
Location in patent: Page/Page column 14-16 ;
反应条件
pyridine in water; benzene
参考文献
Sakiyama,M.; Okawara,R.
Bulletin of the Chemical Society of Japan, 1960 , vol. 33, p. 1645 - 1649
反应条件
Amberlyst 15 cation-exchange resin T=40°C; 85 h;
参考文献
Hasegawa, Isao; Sakka, Sumio
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 12 p. 4313 - 4316
反应条件
bis-trimethylsilyl ether; olivine; water 1.) 5 min; 2.) 1 h; Further byproducts given;
参考文献
Kuroda, Kazuyuki; Koike, Tetsuhiro; Kato, Chuzo
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981 , p. 1957 - 1960
参考文献
Voronkov,M.G. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1975 , vol. 24, p. 579 - 581
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1975 , vol. 24, p. 657 - 660
反应条件
tetrahydrofuran; tetrachlorosilane T=60 - 65°C; 10 h; Product distribution; Further Variations:ReagentsTemperaturesreaction times;
参考文献
Voronkov; Baryshok; Kuznetsova
Russian Journal of Applied Chemistry, 2001 , vol. 74, # 12 p. 2091 - 2094
