1,2-双(二苯基膦)乙烷合成路线 （共 132 条）
反应条件
in benzene byproducts: CO; soln. of Ph2PCH2CH2PPh2 dropped to soln. of (OC)AuCl at room temp. under dry N2, stirred for 1 h (CO removed); filtered;
参考文献
Schmidbaur, Hubert; Inoguchi, Yoshio
Chemische Berichte, 1980 , vol. 113, # 5 p. 1646 - 1653
反应条件
in water; acetone Au-complex was reduced to Au(I) by thiodiglycol in aq. acetone, ligand in acetone was added dropwise over 5 min, stirred for 1 h; ppt. was filtered off, washed with H2O and acetone; elem. anal.;
参考文献
Berners-Price, Susan J.; Mazid, Muhammed A.; Sadler, Peter J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 969 - 974
反应条件
in methanol; dichloromethane N2, stoich., a soln. of gold compd. (methanol) added to a soln. of phosphane (CH2Cl2), stirred for 24 h; solvent removed (vac.), water added, ppt. filtered, washed (water, diethyl ether), dried (vac.);
参考文献
Olkowska-Oetzel, Jolanta; Sevillano, Paloma; Eichhoefer, Andreas; Fenske, Dieter
European Journal of Inorganic Chemistry, 2004 , # 5 p. 1100 - 1106
反应条件
1: With lithium in tetrahydrofuran T=0°C; Metallation; 336 h; 2: With water in tetrahydrofuran T=20°C; Hydrolysis;
参考文献
Butler, Ian R.; Licence, Peter; Coles, Simon J.; Hursthouse, Michael B.
Journal of Organometallic Chemistry, 2000 , vol. 598, # 1 p. 103 - 107
反应条件
in dichloromethane 1.01 mmol (C5H5)Fe(SMe2)3BF4 and 1.01 mmol Ph2P(CH2)2PPh2 in CH2Cl2 mixed at room temp., mixt. stirred for 5 min, filtrated into Et2O; pptd. Fe complex filtered off, dried in vac.; elem. anal.;
参考文献
Kuhn, Norbert; Schumann, Hans; Winter, Manfred; Zauder, Edgar
Chemische Berichte, 1988 , vol. 121, p. 111 - 116
反应条件
in chloroform-d1 mixing at 240 K, standing; not sepd.; NMR spectroscopy;
参考文献
Benito, Monica; Lopez, Concepcion; Morvan, Xavier
Polyhedron, 1999 , vol. 18, # 20 p. 2583 - 2595
参考文献
Societe Nationale des Poudres et Explosifs
Patent: US4709087 A1, 1987 ;
反应条件
1: iodobenzene; (OC)5MoNH2Bn With tributyl-amine in diethylene glycol dimethyl ether T=150°C; 1 h; Inert atmosphere; 2: 1,2-bis-(diphenylphosphino)ethane in diethylene glycol dimethyl ether T=20 - 150°C; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 75, # 9 p. 3017 - 3020
反应条件
palladium diacetate in nitrogen
反应条件
palladium diacetate in nitrogen
