1,2-双(二苯基膦)乙烷合成路线 （共 132 条）
反应条件
in toluene Kinetics; reductive elimination between -19 and 10°C;; monitored by (1)H-NMR-, (13)C-NMR- and (31)P-NMR-spectroscopy;;
参考文献
Journal of the American Chemical Society, , vol. 110, # 18 p. 6272 - 6273
反应条件
palladium diacetate in nitrogen
参考文献
Mitsubishi Kasei Corporation
Patent: US5159082 A1, 1992 ;
反应条件
in toluene Kinetics; reductive elimination bewteen -19 and 10°C;; monitored by (1)H-NMR-, (13)C-NMR- and (31)P-NMR-spectroscopy;;
参考文献
Journal of the American Chemical Society, , vol. 110, # 18 p. 6272 - 6273
反应条件
N2-atmosphere; 3 equiv. of phosphine;
参考文献
Organometallics, , vol. 18, # 11 p. 2145 - 2154
反应条件
in dichloromethane
soln. of dppe was added to a stirred soln. of (Mo(H2CPz'2)(CO)2(π-allyl)Br); reaction was monitored by IR-spectroscopy (every 10 min);; evapn. of solvent (vac.); recrystn. from CH2Cl2/MeOH;;
参考文献
Shiu, Kom-Bei; Yih, Kuang-Hway; Wang, Sue-Lein; Liao, Fen-Ling
Journal of Organometallic Chemistry, 1991 , vol. 414, # 2 p. 165 - 176
反应条件
in dichloromethane
soln. of dppe was added to a stirred soln. of (Mo(H2CPz'2)(CO)2Br2); reaction was monitored by IR-spectroscopy (every 10 min);; evapn. of solvent (vac.); recrystn. from MeOH;;
参考文献
Shiu, Kom-Bei; Yih, Kuang-Hway; Wang, Sue-Lein; Liao, Fen-Ling
Journal of Organometallic Chemistry, 1991 , vol. 414, # 2 p. 165 - 176
反应条件
arsenic(III) iodide in dichloromethane
2 h;
参考文献
Ellis, Bobby D.; Carlesimo, Michelle; Macdonald, Charles L. B.
Chemical Communications, 2003 , # 15 p. 1946 - 1947
反应条件
in tetrahydrofuran
N2 atmosphere; treatment of Pt-complex with equiv. amt. of Ph2PCH=CHPPh2 (room temp., IR minitoring, 2 h); pptn. on n-hexane addn.;
参考文献
Michelin, Rino A.; Bertani, Roberta; Mozzon, Mirto; Zanotto, Livio; Benetollo, Franco; Bombieri, Gabriella
Organometallics, 1990 , vol. 9, p. 1449 - 1459
反应条件
sulfur in chloroform
T=20°C; 1 h; Inert atmosphere;
参考文献
Aizawa, Sen-Ichi; Majumder, Arpi; Maeda, Daisuke; Kitamura, Akina
Chemistry Letters, 2009 , vol. 38, # 1 p. 18 - 19
反应条件
sulfur in tetrahydrofuran
18 h;
参考文献
Faller; Fontaine, Philip P.
Journal of Organometallic Chemistry, 2007 , vol. 692, # 5 p. 976 - 982
