1-(1-环己烯-1-基)-1-丙酮合成路线 （共 21 条）
反应条件
1: AlCl3 / 45 °C 2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol 3: AlCl3 / 1,2-dichloro-ethane / 0.5 h 4: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C 5: SOCl2 / 1 h / Heating 6: 63 percent / pyridine / dimethyl ether / overnight View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C 2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol 3: AlCl3 / 1,2-dichloro-ethane / 0.5 h 4: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C 5: SOCl2 / 1 h / Heating 6: 25percent aq. NH4OH 7: 56 percent / SOCl2, dimethylformamide / 1.5 h / Ambient temperature View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C 2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol 3: AlCl3 / 1,2-dichloro-ethane / 0.5 h 4: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
hydrogen; platinum in ethanol
参考文献
Favorskaya,I.A.; Auvinen,E.M.
Journal of Organic Chemistry USSR (English Translation), 1965 , vol. 1, p. 478 - 480
Zhurnal Organicheskoi Khimii, 1965 , vol. 1, p. 486 - 489
反应条件
potassium hydroxide; zinc
T=15 - 20°C; 1) CH2Cl2, 2) MeOH;
参考文献
Shono, Tatsuya; Nishiguchi, Ikuzo; Sasaki, Manji; Ikeda, Haruhiko; Kurita, Makoto
Journal of Organic Chemistry, 1983 , vol. 48, # 15 p. 2503 - 2505
反应条件
Nafion-H in tetrachloromethane
17 h; Heating;
参考文献
Olah, George A.; Fung, Alexander P.
Synthesis, 1981 , # 6 p. 473 - 474
反应条件
1: LiNEt2
2: aq. KOH
View Scheme
参考文献
Trost,B.M.; Bogdanowicz,M.J.
Journal of the American Chemical Society, 1973 , vol. 95, # 16 p. 5311 - 5321
反应条件
1: 60 percent / Li / tetrahydrofuran / 0 - 10 °C
2: 1.) AlCl3 / 1.) 0 deg C, 1 h, 2.) -90 deg C, CH2Cl2
View Scheme
参考文献
Laguerre, Michel; Grignon-Dubois, Micheline; Dunogues, Jacques
Tetrahedron, 1981 , vol. 37, p. 1161 - 1169
反应条件
1: 75 percent / hexamethylphosphoric acid triamide
2: Na2CO3, frigene 11 / petroleum ether / -30 °C
3: 22 percent Chromat. / SiO2
View Scheme
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
1: Na2CO3, frigene 11 / petroleum ether / -30 °C
2: 22 percent Chromat. / SiO2
View Scheme
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
