(E)-2-甲基-2-戊烯酸乙酯合成路线 （共 17 条）
反应条件
10 Pd/C; hydrogen in methanol P=1500.15 Torr; Inert atmosphere;
参考文献
Li, Jia-Qi; Quan, Xu; Andersson, Pher G.
Chemistry - A European Journal, 2012 , vol. 18, # 34 p. 10609 - 10616
反应条件
1: 10 Pd/C; hydrogen / methanol / 1500.15 Torr / |Inert atmosphere 2: lithium aluminium tetrahydride / |Inert atmosphere View Scheme
参考文献
Li, Jia-Qi; Quan, Xu; Andersson, Pher G.
Chemistry - A European Journal, 2012 , vol. 18, # 34 p. 10609 - 10616
反应条件
sodium hydroxide in methanol 1.5 h; Heating;
参考文献
Rossi; Carpita; Cossi
Synthetic Communications, 1993 , vol. 23, # 2 p. 143 - 152
反应条件
in dichloromethane
T=20°C; Wittig olefination; 1 h;
参考文献
Yadav; Pratap; Rajender
Journal of Organic Chemistry, 2007 , vol. 72, # 15 p. 5882 - 5885
反应条件
1: NaBH4 / ethanol
2: (i) Al(OEt)3, AlCl3, (ii) LDA
View Scheme
参考文献
Katzenellenbogen,J.A.; Utawanit,T.
Journal of the American Chemical Society, 1974 , vol. 96, p. 6153 - 6158
反应条件
(R,R)-t-Bu-BenzP*; dicarbonylacetylacetonato rhodium (I); hydrogen in N-dodecane
T=100°C; P=7500.75 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Wang, Xiao; Buchwald, Stephen L.
Journal of the American Chemical Society, 2011 , vol. 133, # 47 p. 19080 - 19083
反应条件
sulfuric acid
24 h; RefluxInert atmosphere;
参考文献
Li, Jia-Qi; Quan, Xu; Andersson, Pher G.
Chemistry - A European Journal, 2012 , vol. 18, # 34 p. 10609 - 10616
反应条件
1: butyllithium / hexane; diethyl ether / -40 - -30 °C
2: triethylamine / methanol / 6 h / Heating
View Scheme
参考文献
Slougui, Nasser; Rousseau, Gerard; Conia, Jean-Marie
Synthesis, 1982 , # 1 p. 58 - 60
反应条件
1: 1.) diisopropylamine, n-butyllithium / 1.) THF, hexane, -78 deg C, 30 min; 2.) -78 deg C, 15 min; room temp., 1 h
2: butyllithium / hexane; diethyl ether / -40 - -30 °C
3: triethylamine / methanol / 6 h / Heating
View Scheme
参考文献
Slougui, Nasser; Rousseau, Gerard; Conia, Jean-Marie
Synthesis, 1982 , # 1 p. 58 - 60
反应条件
sodium hydride in ethylene glycol dimethyl ether
1.) 0 deg C, 20 min; 2.) RT, 30 min; 3.) reflux, 8h;
参考文献
Huston, Rima; Rey, Max; Dreiding, Andre S.
Helvetica Chimica Acta, 1982 , vol. 65, # 5 p. 1563 - 1575
