1-O-十四烷基甘氨酰蜡素合成路线 （共 10 条）
反应条件
hydrogenchloride; NaH; sodium iodide in tetrahydrofuran; ethyl acetate; N,N-dimethyl-formamide
参考文献
Sky High, LLC
Patent: US6495532 B1, 2002 ;
反应条件
palladium on activated charcoal; hydrogen T=120°C; P=37503.8 Torr; 16 h; AutoclaveInert atmosphere;
参考文献
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; FONDS DE DEVELOPPEMENT DES FILIERES DES OLEAGINEUX ET PROTEAGINEUX FIDOP; Lemaire, Marc; Dayoub, Wissam; Sutter, Marc; Raoul, Yann
Patent: US2014/18579 A1, 2014 ;
Location in patent: Paragraph 0127 ;
反应条件
1: NaH / dimethylformamide / 24 h / Ambient temperature 2: 10percent aq. HCl / 0.5 h / Heating View Scheme
参考文献
Grijalvo, Santiago; Ocampo, Sandra M.; Perales, Jose C.; Eritja, Ramon
Chemistry and Biodiversity, 2011 , vol. 8, # 2 p. 287 - 299
反应条件
1: 78 percent / 48 percent aq. NaOH / TBAB / hexane / 6 h / 45 °C 2: 66 percent / cetyltrimethylammonium permanganate / CH2Cl2 / 5 h / 20 °C View Scheme
参考文献
Anatol,J. et al.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1964 , vol. 258, p. 6466 - 6469
反应条件
glycerol T=190 - 210°C;
参考文献
Henkel and Cie.
Patent: US2028654 , 1933 ;
Full Text Show Details
Henkel and Cie.
Patent: DE615171 , 1932 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 21, p. 1300
Full Text Show Details
Henkel and Cie.
Patent: FR751923 , 1933 ;
反应条件
sodium formate in ethylene glycol Heating;
参考文献
Anatol,J. et al.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1964 , vol. 258, p. 6466 - 6469
反应条件
(i) K, benzene, (ii) /BRN= 1911395/, (iii) aq. HCl, MeOH; Multistep reaction;
参考文献
Aranda, G.; Lallemand, J. Y.
Synthetic Communications, 1990 , vol. 20, # 1 p. 85 - 96
反应条件
sodium hydride 1.) THF, room temperature, 2.) reflux; Multistep reaction;
参考文献
Doren, Henk A. van; Geest, Ralph van der; Kellogg, Richard M.; Wynberg, Hans
Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, # 3 p. 197 - 203
反应条件
in pyridine T=50°C; 18 h;
参考文献
Journal of the American Chemical Society, , vol. 130, # 46 p. 15702 - 15712
反应条件
1: pyridine 2: (i) NaNH2, toluene, (ii) /BRN= 2419977/, toluene, (iii) aq. HCl, iPrOH View Scheme
参考文献
Berecoechea,J.; Anatol,J.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1965 , vol. 260, p. 3700 - 3702
