α-三甲基硅烷基乙烯基溴合成路线 （共 42 条）
反应条件
bromine; diethylamine T=-78°C;
参考文献
Dawson, Ian M.; Gregory, Julian A.; Herbert, Richard B.; Sammes, Peter G.
Journal of the Chemical Society, Chemical Communications, 1986 , # 8 p. 620 - 621
参考文献
Mironov, V. F.; Feoktistov, A. E.; Kozyukov, V. P.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 6 p. 1358 - 1360,1212 - 1214
反应条件
lithium diisopropyl amide in tetrahydrofuran; diethyl ether T=-100°C; 3 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, # 2 p. 777 - 778
反应条件
1: trans vinyl bromide With tert.-butyl lithium in tetrahydrofuran; diethyl ether; pentane T=-110°C; 2: chloro-trimethyl-silane in tetrahydrofuran; diethyl ether; pentane
参考文献
Organic Letters, , vol. 5, # 13 p. 2263 - 2266
反应条件
1: trans vinyl bromide With n-butyllithium; lithium bromide in tetrahydrofuran; diethyl ether; pentane T=-110 - -108°C; 0.75 h; 2: propionaldehyde in tetrahydrofuran; diethyl ether; pentane T=-105 - -100°C; 1 h; 3: chloro-trimethyl-silane in tetrahydrofuran; diethyl ether; pentane Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 5, # 13 p. 2263 - 2266
反应条件
lithium diisopropyl amide T=-75°C; 2 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, # 2 p. 777 - 778
反应条件
1: trans vinyl bromide With n-butyllithium; lithium bromide in tetrahydrofuran; diethyl ether; pentane T=-110°C; 2: chloro-trimethyl-silane; heptanal in tetrahydrofuran; diethyl ether; pentane T=-115°C;
参考文献
Journal of Organic Chemistry, , vol. 70, # 25 p. 10247 - 10259
参考文献
Journal of Organic Chemistry, , vol. 43, p. 1526 - 1532
反应条件
(i) Br2, CCl4, (ii) NaHCO3, MeOH; Multistep reaction;
参考文献
Chemische Berichte, , vol. 110, p. 867 - 877
参考文献
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 1954,1958;engl.Ausg.S.1864,1868
