nitrogen in not given react. of PH3 with H2O-vapor to H3PO4, H3PO3 and H2; slow react. at low temp. under pressure; fast react. at 300-350°C; acceleration by compressed N2;;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 215, p. 388 - 414
methyltrioxorhenium (VII) in water Kinetics; byproducts: t-BuOCH3, t-BuOOCH3, CH3OH; 0.1 M CF3SO3Na, 22.5°C; further byproduct: Me2CO; not isolated, reaction followed by (1)H-NMR spectroscopy;
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of HNO3; not isolated, reaction followed by UV/VIS spectroscopy;
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of bromate; not isolated, reaction followed by UV/VIS spectroscopy;
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of chlorate; not isolated, reaction followed by UV/VIS spectroscopy;
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of HClO4; not isolated, reaction followed by UV/VIS spectroscopy;
HCl or CH3COCl or PCl3 in neat (no solvent) byproducts: P, phosphorus hydride; reaction of H3PO2 with HCl or CH3COCl or PCl3;; impured with amorphous P and solid phosphorus hydride;;
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of HBrO4; not isolated, reaction followed by UV/VIS spectroscopy;
