in neat (no solvent) byproducts: phosphorus hydrides; decompn. at ambient pressure; at first formation of H4P2O5 and H2O; decompn. of H4P2O5 forming H4P2O7, HPO3, PH3 and a small amount of solid phosphorus hydrides;;
in neat (no solvent) heating in CO2 atmosphere to 100°C there is slow pptn. of yellow material, at higher temperatures there is very fast pptn. of first yellow then orange colored mixture of red P and solid (P2H)(x);;
参考文献
Amat, L.
Ann. Chim. Phys., 1891 , vol. 24, p. 289 - 373
in neat (no solvent) byproducts: phosphorus hydrides; decompn. below 10 Torr; at first formation of H4P2O5 and H2O; decompn. of H4P2O5 forming H4P2O7, HPO3, PH3 and yellow-orange solid phosphorus hydrides; further decompn. of solid phosphorus hydrides forming PH3 and red P;;
in propionic acid not isolated; (31)P-NMR spectroscopic monitoring;
参考文献
Kardanov, N. A.; Godovikov, N. N.; Petrovskii, P.V.; Fedin, E. I.; Kabachnik, M. I.
Doklady Chemistry, 1983 , vol. 268, p. 12 - 16
Dokl. Akad. Nauk SSSR Ser. Khim., 1983 , vol. 268, # 2 p. 364 - 368
