hydrogen; triphenylphosphine; [bmim][SbF6]; [rhodium(I)(carbonyl)2(acetylacetonate)] in isopropyl alcohol P=15001.2 Torr; Yield given. Title compound not separated from byproducts;
hydrogen; cobaltcluster T=150°C; P=51154.1 - 57829.6 Torr; 22.5 h; determination of selectivity, velocity and decomposition of cluster; also with phosphanes; other temperatures, pressures and times; MechanismProduct distribution;
1: in acetonitrile-D3 3 h; 2: With water; sodium acetate; acetic acid
参考文献
Hodgson, David M.; Bray, Christopher D.; Kindon, Nicholas D.; Reynolds, Nigel J.; Coote, Steven J.; Um, Joann M.; Houk
Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1019 - 1028