1,1'-双(二苯基膦)二茂铁合成路线 （共 33 条）
反应条件
tributylphosphine; iodine in tetrahydrofuran; acetonitrile T=20°C; 0.166667 h; Inert atmosphere;
参考文献
WO2011/123037 A1, ;
Page/Page column 23 ;
反应条件
1: biscyclopentadienyliron(II) With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane T=20°C; Inert atmosphere; 2: chloro-diphenylphosphine in tetrahydrofuran; dichloromethane T=-78 - 20°C; 3 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 18, # 39 p. 12267 - 12277
反应条件
in not given Fe complex was added to large excess of Li compd.; elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 185, # 1 p. C1 - C5
反应条件
in tetrahydrofuran (Ar); dropwise addn. of a soln. of trisubstituted lithium compd. in THF to a suspn. of iron salt in THF at -40°C, stirring for 2 h at room temp., addn. of a soln. of monosubstituted lithium salt in THF at -40°C; evapn., reflux in toluene for 3 h, cooling, filtration, column chromy. (SiO2, toluene/hexane 4:1); elem. anal.;
参考文献
Organometallics, , vol. 25, # 4 p. 989 - 995
反应条件
in acetonitrile (N2); stirring a mixt. of ruthenium complex and NaNCS in acetonitrile for 2 d; filtration, concn., addn. of ether, cooling to 0°C for 3 h; elem.anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 689, # 11 p. 1978 - 1990
反应条件
in acetonitrile (N2); addn. of phosphine to a soln. of ruthenium complex in acetonitrile, stirring for 8 h; filtration, concn.; elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 689, # 11 p. 1978 - 1990
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine; sodium hydrogencarbonate in diethyl ether; hexane Ar-atmosphere; addn. of BuLi (2.1 equivs.) to ferrocene derivative, addn. of TMEDA, stirring (>=20 h), addn. of ClPPh2, stirring (room temp., 10 h); addn. of aq. NaHCO3, extn. (CH2Cl2), solvent removal, chromy. (Al2O3, hexanes/Et2O=8:2); elem. anal.;
参考文献
Organometallics, , vol. 5, p. 2537 - 2542
反应条件
in methanol (N2); refluxing a suspn. of ruthenium complex and ligand in MeOH for 10 h; filtration, washing with methanol, ether, drying in vac., recrystn. (CH2Cl2/hexane, 0°C, 1 h); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 689, # 11 p. 1978 - 1990
反应条件
in hexane; benzene under N2; dropwise addn. of PhSPPh2 in benzene to hexane soln. of complex over 30 min with stirring at -50°C, stirred at room temp. overnight; addn. of H2O, ppt. filtered off, washed (H2O, hexane), recrystd. (CH2Cl2);
参考文献
Organometallics, , vol. 11, p. 2543 - 2550
反应条件
in diethyl ether Ar-atmosphere; excess PhLi; mixing at -70°C, warming to room temp.; H2O addn. (cooling), drying of Et2O layer (MgSO4), partial evapn. (vac.), crystn. (hexanes);
参考文献
Organometallics, , vol. 5, p. 2537 - 2542
