2,3-二甲基-3-丁烯-2-醇合成路线 （共 74 条）
反应条件
1: t-BuOK, 18-couronne-6 / benzene / Heating
2: Na / liquid ammonia
View Scheme
参考文献
Rodriguez, J.; Dulcere, J-P; Bertrand, M.
Tetrahedron Letters, 1984 , vol. 25, # 5 p. 527 - 528
反应条件
perchloric acid; sodium nitrite in water
1 h; Further byproducts given;
参考文献
Guenther, Bernd-Rainer; Kirmse, Wolfgang
Liebigs Annalen der Chemie, 1980 , # 4 p. 518 - 532
反应条件
oxygen; silica gel; triphenylphosphine
T=30°C; 70 h; Irradiationchange the metal oxide, atmosphere, irradiation time; Product distribution;
参考文献
Gohre, Kirk; Miller, Glenn C.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1985 , vol. 81, p. 793 - 800
反应条件
potassium tert-butylate; tert-butyl alcohol
336 h; Ambient temperature;
参考文献
Goldmann, Siegfried
Synthesis, 1980 , # 8 p. 640 - 642
反应条件
trans,cis-Pt(PEt3)2Cl2(OH)(9-phenanthryl); oxygen in benzene-d6
Photolysis;
参考文献
Wickramasinghe, Lasantha A.; Sharp, Paul R.
Inorganic Chemistry, 2014 , vol. 53, # 3 p. 1430 - 1442
反应条件
perchloric acid; sodium nitrite in water
1 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Guenther, Bernd-Rainer; Kirmse, Wolfgang
Liebigs Annalen der Chemie, 1980 , # 4 p. 518 - 532
反应条件
perchloric acid; sodium nitrite in water
1 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Guenther, Bernd-Rainer; Kirmse, Wolfgang
Liebigs Annalen der Chemie, 1980 , # 4 p. 518 - 532
反应条件
perchloric acid; sodium nitrite in water
1 h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Guenther, Bernd-Rainer; Kirmse, Wolfgang
Liebigs Annalen der Chemie, 1980 , # 4 p. 518 - 532
反应条件
1: 1. Diisopropylamin, 15percent Butyllithium/Hexan / - 78 deg C, 10 min., THF
2: 35 percent / 1M tert-BuOK/tert-BuOH / 336 h / Ambient temperature
View Scheme
参考文献
Goldmann, Siegfried
Synthesis, 1980 , # 8 p. 640 - 642
反应条件
trans,cis-Pt(PEt3)2(Cl)2(OH)(4-trifluoromethylphenyl) in dichloromethane-d2
0.0833333 h; PhotolysisInert atmosphere; Reagent/catalyst;
参考文献
Wickramasinghe, Lasantha A.; Sharp, Paul R.
Inorganic Chemistry, 2014 , vol. 53, # 3 p. 1430 - 1442
